172513-48-3

Basic information

• Product Name: 2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-3-methyl-butan-1-one
• Synonyms: 2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-3-methyl-butan-1-one
• CAS NO: 172513-48-3
• Molecular Weight: 392.434
• Mol File: 172513-48-3.mol

Chemical Properties

• CAS DataBase Reference: 2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-3-methyl-butan-1-one(CAS DataBase Reference)
• NIST Chemistry Reference: 2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-3-methyl-butan-1-one(172513-48-3)
• EPA Substance Registry System: 2-(Diphenyl-phosphinoyl)-1-(4-methoxy-phenyl)-3-methyl-butan-1-one(172513-48-3)

Safety Data

• Hazardous Substances Data: 172513-48-3(Hazardous Substances Data)

Upstream product

• 123-11-5 4-methoxy-benzaldehyde 
• 63103-76-4 diphenyl 2-methylpropyl phosphine oxide 

Downstream Products

• 103786-20-5 (E)-1-methoxy-4-(3-methyl-but-1-en-1-yl)benzene 

Relevant articles and documents

The stereoselective Horner-Wittig reaction with phoshine oxides: Synthesis of hindered Z alkenes via Luche reduction

The natural anti selectivity of the Horner-Wittig reaction with phospine oxides is reduced when there is a branched chain next to the new C=C double bond. A better approach is Luche reduction of the corresponding ketones which gives high anti selectivity when the branched chain is placed on the side chain next to the phosphine oxide.