103786-20-5

Basic information

• Product Name: Benzene, 1-methoxy-4-[(1E)-3-methyl-1-butenyl]-
• CAS NO: 103786-20-5
• Molecular Formula: C12H16O
• Molecular Weight: 176.258
• Mol File: 103786-20-5.mol
• Article Data: 24

Chemical Properties

• CAS DataBase Reference: Benzene, 1-methoxy-4-[(1E)-3-methyl-1-butenyl]-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-methoxy-4-[(1E)-3-methyl-1-butenyl]-(103786-20-5)
• EPA Substance Registry System: Benzene, 1-methoxy-4-[(1E)-3-methyl-1-butenyl]-(103786-20-5)

Safety Data

• Hazardous Substances Data: 103786-20-5(Hazardous Substances Data)

Upstream product

• 1468-39-9 Isovaleric anhydride 
• 123-11-5 4-methoxy-benzaldehyde 
• 18272-88-3 1-methoxy-4-(2-methylbut-3-en-2-yl)benzene 
• 75-30-9 2-iodo-propane 
• 3179-10-0 (E)-1-methoxy-4-(2-nitrovinyl)benzene 
• 10288-13-8 1,2-dibromo-3-methylbutane 
• 5720-07-0 4-methoxyphenylboronic acid 
• 1309466-59-8 C₁₇H₂₇O₄PS 
• 75-16-1 methylmagnesium bromide 
• 131161-70-1 1-(2-cyclopropylethyl)-4-methoxybenzene 
• 14425-64-0 4-methoxyphenethyl bromide 
• 3179-10-0 1-methoxy-4-(2-nitro-vinyl)-benzene 
• 1539-32-8 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester 
• 943-89-5 (E)-3-(4-methoxyphenyl)acrylic acid 

Downstream Products

• 622-67-3 1-methoxy-4-(3-methylbutyl)benzene 
• 1805-61-4 p-isoamylphenol 
• 4097-51-2 4-isopentyl-2,6-dinitro-phenol 

Relevant articles and documents

Visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones

Herein we report a mild, general protocol for visible-light-mediated alkylation of 4-alkyl-1,4-dihydropyridines with alkenyl sulfones. The protocol permits efficient functionalization of sulfones with a broad range of cyclic and acyclic secondary and tert

A Highly Reduced Ni-Li-Olefin Complex for Catalytic Kumada-Corriu Cross-Couplings

The catalytic activity of a highly reduced Ni catalyst in the context of a Kumada-Corriu cross-coupling has been studied. This nickel complex is characterized by its high electron density, stabilized by simple olefin ligands in combination with two Li ions. Landmark reactivity has been found with this precatalyst which operates at cryogenic temperatures, thus allowing the presence of sensitive functionalities. Structural elucidation of oxidative addition intermediates and their reactivity suggest highly reduced species being operative in the C-C bond forming event.

Copper- and Nickel-Catalyzed Cross-Coupling Reaction of Monofluoroalkenes with Tertiary, Secondary, and Primary Alkyl and Aryl Grignard Reagents

A highly efficient cross-coupling reaction of monofluoroalkenes with tertiary, secondary, and primary alkyl and aryl Grignard reagents in the presence of a catalytic amount of copper or nickel catalyst, respectively, has been developed. The reactions proceeded smoothly at room temperature, providing (E)-alkene isomers in moderate to high yields. Plausible mechanisms of the Ni-catalyzed coupling reaction of monofluoroalkene with Grignard reagents are suggested.