1726-03-0Relevant articles and documents
Desulfurization of benzylic mercaptans by triiron dodecacarbonyl under acidic and biphasic conditions
Alper, Howard,Sibtain, Fazle
, p. 225 - 229 (2007/10/02)
The biphasic reaction of benzylic mercaptans with triiron dodecacarbonyl, 48-50% tetrafluoroboric acid, and benzene affords desulfurized products in good to excellent yields. This reaction is superior to that effected in the presence of sodium dodecylbenzenesulfonate, a phase transfer agent for acidic processes.
PHASE TRANSFER CATALYZED DESULFURIZATION REACTIONS
Alper, Howard,Sibtain, Fazle,Heveling, Josef
, p. 5329 - 5332 (2007/10/02)
Mercaptans react with triiron dodecarbonyl or dicobalt octacarbonyl, under phase transfer catalysis conditions, to give hydrocarbons in good yields.