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Praseodymium(III) chloride hexahydrate, with the chemical formula PrCl3·6H2O, is a green crystalline solid that is highly soluble in water. It is a rare earth metal compound known for its various industrial and research applications. The hexahydrate form of praseodymium(III) chloride is significant as it influences the compound's physical and chemical properties, making it more suitable for specific uses. This valuable compound plays a crucial role in the field of materials science and catalysis.

17272-46-7

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17272-46-7 Usage

Uses

Used in Organic Synthesis:
Praseodymium(III) chloride hexahydrate is used as a catalyst in organic synthesis reactions for its ability to facilitate and enhance the efficiency of various chemical processes. Its catalytic properties make it a valuable component in the synthesis of complex organic molecules.
Used in Materials Science:
In the field of materials science, praseodymium(III) chloride hexahydrate is used as a precursor for the production of other praseodymium compounds. These compounds are essential in developing advanced materials with unique properties, such as high-strength alloys, magnets, and phosphors.
Used in Research Applications:
Praseodymium(III) chloride hexahydrate is also utilized in research applications, where its unique properties are explored and harnessed for the development of new technologies and understanding of chemical reactions. Its role in research contributes to the advancement of knowledge in the fields of chemistry, physics, and materials science.

Check Digit Verification of cas no

The CAS Registry Mumber 17272-46-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 1,7,2,7 and 2 respectively; the second part has 2 digits, 4 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 17272-46:
(7*1)+(6*7)+(5*2)+(4*7)+(3*2)+(2*4)+(1*6)=107
107 % 10 = 7
So 17272-46-7 is a valid CAS Registry Number.
InChI:InChI=1/ClH.6H2O.Pr/h1H;6*1H2;/q;;;;;;;+3/p-1

17272-46-7Relevant academic research and scientific papers

Solubility in the LaCl3-LnCl3-HCl-H2O (Ln = Pr, Nd) systems at 25°C

Knyazeva,Skiba,Serba

, p. 592 - 595 (2012/07/14)

The solubility in the quaternary water-salt systems LaCl 3-NdCl3-HCl-H2O (1) and LaCl3- PrCl3-HCl-H2O (2) at 25°C was studied in the section of 40 wt % hydrochloric acid, a system with a eutonic discontinuity. The composition at the point of discontinuity for the eutonic solution is the following. In system 1: 4.67 wt % LaCl3 · 7H2O, 0.37 wt % PrCl3 · 7H2O, 37.98 wt % HCl, and 56.98 wt % H2O; in system 2: 4.37 wt % LaCl3 · 7H 2O, 0.93 wt % NdCl3 · 6H2O, 37.88 wt % HCl, and 56.82 wt % H2O.

Synthesis, structure, thermal and luminescent behaviors of lanthanide-Pyridine-3,5-dicarboxylate frameworks series

?yszczek, Renata

, p. 120 - 127 (2011/01/08)

The isostructural series of lanthanide pyridine-3,5-dicarboxylates of the formula [Ln2pdc3(dmf)2]·(dmf) x(H2O)y where Ln are lanthanides from La(III) to Lu(III); pdc2--C5/s

Solubility in the PrCl3-SmCl3-HCl-H2O System at 25°C

Knyazeva,Skiba,Voskoboinikov

, p. 125 - 127 (2009/05/06)

The solubility in the PrCl3-SmCl3-HCl-H2O quaternary water-salt system was studied at 25°C along the 40% hydrochloric acid section (a system with solid solutions and discontinuity). The composition of the discontinuity poi

Synthesis, crystal structures and properties of a series of three-dimensional lanthanide coordination polymers with the rigid and flexible mixed dicarboxylate ligands of 1,4-benzene dicarboxylic acid and succinic acid

Wang, Chun-Guang,Xing, Yong-Heng,Li, Zhang-Peng,Li, Jing,Zeng, Xiao-Qing,Ge, Mao-Fa,Niu, Shu-Yun

, p. 126 - 131 (2009/08/15)

A series of new lanthanide coordination polymers, with the formula [Ln(Suc)0.5(p-BDC)] (Ln = Eu (1), Sm (2), Tb (3), Pr (4), Ho (5); H2Suc = succinic acid; p-H2BDC = 1,4-benzene dicarboxylic acid), have been synthesized un

Phase equilibrium system of RbCl-PrCl3-HCl(12.86 mass %)-H 2O at 298.15 K and standard molar enthalpy of formation of new solid-phase compound

Qiao, Zhanping,Gao, Junlin,Zhuo, Lihong,Zhang, Meili,Zhang, Shuai

, p. 1474 - 1478 (2009/12/04)

The equilibrium solubility of the quaternary system RbCl-PrCl 3-HCl-H2O was determined at 298.15 K and the corresponding equilibrium diagram was constructed in this paper. The quaternary system is complicated with three equilibrium s

Synthesis, structure, and antibacterial properties of ternary rare-earth complexes with o-methylbenzoic Acid and 1,10-phenanthroline1

Chen,Wang,Yang,Zhao,Zhang,Wang,Zhao

, p. 541 - 546 (2009/12/02)

Ternary rare-earth complexes with o-methylbenzoic acid (o-MBA) and 1,10-phenanthroline (Phen) Ln2(o-MBA)6(Phen)2 ? nH2O(n = 0, 1) (Ln = La, Pr, Y, Yb) were synthesized and characterized by elemental analysis, IR

Syntheses and characterization of novel lanthanide adamantine-dicarboxylate coordination complexes

Li, Xing,Wei, Dan-Yi,Huang, Shi-Jie,Zheng, Yue-Qing

, p. 95 - 101 (2009/04/14)

Hydrothermal reactions of 1,10-phenanthroline (phen), 1,3-adamantanedicarboxylic acid (H2L) and lanthanide chlorides yielded six compounds: [Ln(L)(HL)(phen)] (Ln=Pr, 1; Nd, 2), [Ln(L)(HL)(phen)(H2O)] (Sm, 3; Eu, 4), [Tb(L)(HL)(phen)(

Synthesis, structure and properties of [Pr(DMSO)5(H 2O)2](μ-CN)[Co(CN)5]·H2O

Chen, Wen-Tong,Zeng, Xi-Rui,Xu, Ya-Ping,Luo, Qiu-Yan,Chen, Hua-Long

, p. 32 - 36 (2008/09/19)

A new cyano-bridged praseodymiumIII-cobaltIII complex [Pr(DMSO)5(H2O)2](μ-CN)[Co(CN) 5]·H2O, (1), has been synthesized via solution reaction and characterized by X-ray diffraction. The slightly distorted square-antiprism eightfold-coordinated Pr(III) and the approximately oriented octahedrally sixfold-coordinated Co(III) are linked by a cyano-bridge group to form a dinuclear complex. The [Pr(DMSO)5(H2O) 2](μ-CN)[Co(CN)5] species are held together via hydrogen bonds to form a two-dimensional slab. The magnetic properties show that complex 1 exhibits antiferromagnetic interactions. IR and thermogravimetry- differential thermal analyses (TG-DTA) are also presented.

Reassignment of the crystal space group of crystalline Pr[M(CN)6] · 5H2O (M = Cr, Fe, Co)

Zhang, Lin-Ping,Zhou, Xian-ju,Mak, Thomas C.W.,Tanner, Peter A.

, p. 4019 - 4023 (2008/10/09)

Refinement of the X-ray crystal structures of Pr[M(CN)6] · 5H2O (M = Cr, Fe, Co) enables their space group to be reassigned to P63/mmc. Spectral characteristics are reported for M = Cr and the distinction between the penta

Two novel R- and S-malato-bridged coordination polymers by reacting lanthanide chloride and maleic anhydride, 1,10-phenanthroline at hydrothermal condition

Zhang, Li-Ping,Huang, Liang,Qu, Ling-bo,Peng, Hua,Zhao, Yu-Fen

, p. 14 - 17 (2007/10/03)

Two less common lanthanide coordination polymers, [Ln2(fum)(malate)2(phen)2]n ·n1.25H2O (Ln=Eu, 1; Pr, 2. fum=fumarate, phen=1,10-phenanthroline) were synthesized and characterized by IR spectra and X-ray crystallography. Single crystal X-ray diffraction analysis shows that complex 1 is isostructural with complex 2. In the two complexes, we found a pair of enantiomers (R-malate and S-malate) which are obtained by addition reaction between maleate and water and fumarate which result from configurational tranformation of maleate. The two structures consist of coordination polymer chains along the c-axis which are held together solely through hydrogen bonding and π-π stacking. Three-dimension supramolecular structures are formed through the two types of weak interaction. The IR data are also described and compared with those of other similar complexes.

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