17299-41-1Relevant academic research and scientific papers
A General Preparative Method for Carbonyl-Protected γ-Lithioketones via Reductive Lithiation. Synthetic Uses of the Bishomoenolate Equivalents
Cohen, Theodore,Zhang, Birong,Cherkauskas, John P.
, p. 11569 - 11584 (2007/10/02)
The mixed cuprates, generated by reductive lithiation of bis(phenylthio)acetals using lithium 4,4'-di-tert-butylbiphenylide (LDBB), followed by addition of cuprous bromide-dimethyl sulfide complex, undergo conjugate addition to enones in the presence of t
Synthesis of three new compounds structurally related to damascone and ionone
Witteveen, Jan G.,Weerdt, Anton J. A. van der
, p. 383 - 386 (2007/10/02)
1-(3,6,6-Trimethyl-1,3-cyclohexadien-1-yl)-2-buten-1-one (1), a β-damascenone isomer, was synthesized from 3,6,6-trimethyl-2-cyclohexenone (14).This starting ketone 14 was obtained in good yield from 3-methyl-2-butanone (11) and 3-buten-2-one (12).Ethynyl
Alkyl Substituent Effects on the Photorearrangement of Cyclohex-2-en-1-ones to Lumiketones
Schuster, David I.,Rao, Jampani Madhusudana
, p. 1515 - 1521 (2007/10/02)
The effect of alkyl substitution on the photorearrangement of cyclohex-2-en-1-ones to bicyclohexan-2-ones (lumiketones) was investigated.Contrary to earlier reports, both 2,4,4- and 3,4,4-trimethylcyclohex-2-en-1-one undergo this rearrangement upon
