17333-84-5

Usage

Preparation

1-Chloro-3-nitrobenzene reduction.

InChI:InChI=1/C6H4ClN2/c7-5-2-1-3-6(4-5)9-8/h1-4H/q+1

Upstream product

• 64-17-5 ethanol 
• 108-42-9 3-chloro-aniline 
• 110-46-3 isopentyl nitrite 

Downstream Products

• 106475-43-8 3-(3-chloro-phenyl)-1-isopropyl-pyrrole-2,5-dione 
• 107153-98-0 3'-Chlor-4-dimethylamino-2-methyl-azobenzol 
• 17596-04-2 1,3-bis-(3-chloro-phenyl)-triazene 
• 6657-02-9 4-(3-chloro-phenylazo)-phenol 
• 15426-14-9 3,3'-dichloroazobenzene 
• 541-73-1 1,3-Dichlorobenzene 
• 14763-20-3 3-chlorophenyl hydrazine 
• 2888-06-4 3-chlorophenylsulfonyl chloride 
• 5410-26-4 m-chlorophenylarsonic acid 
• 3296-06-8 1-azido-3-chlorobenzene 
• 108-43-0 3-monochlorophenol 
• 108-37-2 1-bromo-3-chlorobenzene 
• 766-84-7 3-chloro-benzonitrile 
• 94602-23-0 dithiophosphoric acid O,O'-diethyl ester-S-(3-chloro-phenyl ester) 

Relevant academic research and scientific papers

Modifying a known gelator scaffold for nitrite detection

The process of selecting and modifying a known gelator scaffold to develop a new nitrite-based sensor is described. Five new azo-sulfonate gelators were discovered and characterized. The most promising scaffold exhibits a stable diazonium intermediate, proceeds in a high yield, and gels nitrite-spiked tap, river, and pond water. This journal is the Partner Organisations 2014.

Mechanism of the Oxidation of NADH by Quinones. Energetics of One-Electron and Hydride Routes

The kinetics of NADH oxidation by 7 o-benzoquinones and 14 p-benzoquinones were studied by using buffered aqueous solutions and UV/vis spectroscopy.For each quinone the rate law was first order in NADH and first order in quinone.The rate constants varied from 0.0745 to 9220 M-1s-1.Variation of the pH from 6 to 8 gave no change in rate.The use of 4-D and 4,4-D2NADH revealed kinetic isotope effects.The dideutero data gave kH/kD in the range 1.6-3.1 for p-quinones and 4.2 for 3,5-di-tert-butyl-o-quinone.When p-quinones were used, the log k was a linear function of Eo for the quinone/hydroquinone monoanion (Q/QH(1-)) couple with a slope of 16.9 V-1. o-Quinones reacted about 100 times more rapidly, but the same linear relationship with a slope of 16.4 V-1 was observed.Comparisons to data for one-electron-transfer reactions indicate that such mechanisms are not involved.A hydride-transfer mechanism accommodates all the data, and rate-limiting hydrogen atom transfer followed by electron transfer cannot be ruled out.