17342-56-2

Basic information

• Product Name: 1,3-Diphenyl-2-butene
• Synonyms: 1,3-Diphenyl-2-butene
• CAS NO: 17342-56-2
• Molecular Formula: C₁₆H₁₆
• Molecular Weight: 208.3
• Mol File: 17342-56-2.mol

Chemical Properties

• Appearance: /
• CAS DataBase Reference: 1,3-Diphenyl-2-butene(CAS DataBase Reference)
• NIST Chemistry Reference: 1,3-Diphenyl-2-butene(17342-56-2)
• EPA Substance Registry System: 1,3-Diphenyl-2-butene(17342-56-2)

Safety Data

• Hazardous Substances Data: 17342-56-2(Hazardous Substances Data)

Upstream product

• 100-42-5 styrene 
• 16606-47-6 2,4-diphenylbut-1-ene 
• 1083-30-3 dihydrochalcone 
• 34636-09-4 benzyldiisopropylamine 
• 98-83-9 isopropenylbenzene 
• 1504-72-9 ethyl 3-phenylbut-2-enoate 
• 98-86-2 acetophenone 
• 54976-37-3 3-phenylbut-2-en-1-ol 
• 98-80-6 phenylboronic acid 
• 122-57-6 1-Phenylbut-1-en-3-one 
• 26138-28-3 phenylytterbium iodide 
• 77073-63-3 2-[(E)-3-(tert-Butyl-dimethyl-silanyloxy)-1-methyl-propenylsulfanyl]-pyridine 

Downstream Products

• 1520-44-1 1,3-diphenylbutane 

Relevant articles and documents

Iron-Catalyzed Highly Enantioselective Hydrogenation of Alkenes

Here, we reported for the first time an iron-catalyzed highly enantioselective hydrogenation of minimally functionalized 1,1-disubstituted alkenes to access chiral alkanes with full conversion and excellent ee. A novel chiral 8-oxazoline iminoquinoline ligand and its iron complex have been designed and synthesized. This protocol is operationally simple by using 1 atm of hydrogen gas and shows good functional group tolerance. A primary mechanism has been proposed by the deuterium-labeling experiments.

Nickel-Catalyzed Benzylation of Aryl Alkenes with Benzylamines via C-N Bond Activation

We have developed the first example of nickel-catalyzed Heck-type benzylation of aryl olefins with various benzylamines as benzyl electrophiles, and the benzylic C-N bond cleavage was efficiently promoted by the amine-I2 charge transfer complex (CT complex). The combination of low-cost NiCl2 and I2 has been found to facilitate Heck reaction of tertiary benzylamines and alkenes into various benzyl-substituted alkenes in good to excellent yields. This unconventional Heck reaction is proposed to go through initially the formation of a benzylic radical via oxidative addition of the C-N bond with Ni(0), then capturing by aryl alkene via radical addition, followed by single-electron transfer redox and proton abstraction without oxidant and external base.

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcohols with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcohols using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcohols (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence.

COMPOUNDS CAPABLE OF RELEASING FRAGRANT COMPOUNDS

Provided is class of compounds of formula (I) wherein X, R1, R2 and R3 have the same meaning as given in the specification capable of releasing fragrant compounds in a controlled manner into the surroundings.

HIGHLY STEREOSELECTIVE SYNTHESIS OF TRISUBSTITUTED OLEFINS FROM ALKENYL ARYL SULFOXIDES

Alkenyl aryl sulfoxides could be alkylated stereoselectively via their lithium salts to afford α-alkylated (E)-alkenyl sulfoxides.Reduction of the sulfoxides to the corresponding sulfides followed by nickel-phosphine complexes catalyzed coupling reaction