17403-83-7Relevant academic research and scientific papers
SILICON-BASED CROSS COUPLING AGENTS AND METHODS OF THEIR USE
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Paragraph 0056, (2016/02/10)
Compositions and methods using silicon-based cross-coupling agents in the formation of carbon-carbon and carbon-nitrogen bonds are described.
SILICON-BASED CROSS COUPLING AGENTS AND METHODS OF THEIR USE
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Paragraph 0050, (2014/01/08)
Compositions and methods using silicon-based cross-coupling agents in the formation of carbon-carbon and carbon-nitrogen bonds are described.
Unification of anion relay chemistry with the Takeda and Hiyama cross-coupling reactions: Identification of an effective silicon-based transfer agent
Smith III, Amos B.,Hoye, Adam T.,Martinez-Solorio, Dionicio,Kim, Won-Suk,Tong, Rongbiao
supporting information; experimental part, p. 4533 - 4536 (2012/04/23)
The unification of Anion Relay Chemistry (ARC) with the Takeda and Hiyama palladium-mediated cross-coupling processes to provide aryl-aryl, alkenyl-aryl, and alkenyl-alkenyl coupled products by exploiting a common silicon-based transfer agent has been achieved. These results provide a practical solution for intermolecular cross-coupling of organolithium reagents without the problematic lithium-halogen exchange and/or undesired homocoupling that has kept organolithium cross-couplings from achieving the same level of utility asother palladium-mediated methods (e.g., Suzuki organoboron, Negishi organozinc, Stille organotin, Kumada organomagnesium, etc.).
Stereoselective cis-addition of aromatic C - H bonds to alkynes catalyzed by dinuclear palladium complexes
Tsukada, Naofumi,Mitsuboshi, Tomohiro,Setoguchi, Hiroyuki,Inoue, Yoshio
, p. 12102 - 12103 (2007/10/03)
Reactions of alkynes with arenes proceeded in the presence of dinuclear palladium complexes and trialkylboranes to yield alkyne hydroarylation products with high stereoselectivity. In the reactions of monosubstituted benzenes, meta and para products were
Palladium-Catalyzed Cross-Coupling of Silanols, Silanediols, and Silanetriols Promoted by Silver(I) Oxide
Hirabayashi, Kazunori,Mori, Atsunori,Kawashima, Jun,Suguro, Masahiro,Nishihara, Yasushi,Hiyama, Tamejiro
, p. 5342 - 5349 (2007/10/03)
Palladium-catalyzed cross-coupling of aryl- or alkenylsilanols, silanediols, and silanetriols with a variety of iodoarenes by the catalysis of palladium(0) and in the presence of silver(I) oxide furnished the coupling products in good to excellent yields. The reactions of silanediols or silanetriols under similar conditions proceeded much faster than those of silanols to afford the corresponding coupling products in excellent yields within shorter reaction periods (5-12 h). The measurement of the X-ray diffraction (XRD) pattern of the silver residue after the reaction revealed that silver(I) oxide was converted to silver(I) iodide.
