174357-47-2

Basic information

• Product Name: (aR)-2,2'-dibenzyloxy-6,6'-dimethoxy-1,1'-binaphthyl
• Synonyms: (aR)-2,2'-dibenzyloxy-6,6'-dimethoxy-1,1'-binaphthyl
• CAS NO: 174357-47-2
• Molecular Weight: 526.632
• Mol File: 174357-47-2.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: (aR)-2,2'-dibenzyloxy-6,6'-dimethoxy-1,1'-binaphthyl(CAS DataBase Reference)
• NIST Chemistry Reference: (aR)-2,2'-dibenzyloxy-6,6'-dimethoxy-1,1'-binaphthyl(174357-47-2)
• EPA Substance Registry System: (aR)-2,2'-dibenzyloxy-6,6'-dimethoxy-1,1'-binaphthyl(174357-47-2)

Safety Data

• Hazardous Substances Data: 174357-47-2(Hazardous Substances Data)

Upstream product

• 100-39-0 benzyl bromide 
• 67-56-1 methanol 
• 163959-71-5 (aR)-2,2'-dibenzyloxy-6,6'-dibromo-1,1'-binaphthyl 
• 79082-80-7 (S)-6,6'-dibromo-1,1'-binaphthalene-2,2'-diol 

Downstream Products

• 174357-51-8 (aR)-6,6'-dimethoxy-3-formyl-2-methoxymethoxy-2'-phenyl-1,1'-binaphthyl 
• 174357-50-7 (aR)-6,6'-dimethoxy-2-methoxymethoxy-2'-phenyl-1,1'-binaphthyl 
• 174357-49-4 (aR)-6,6'-dimethoxy-2-hydroxy-2'-phenyl-1,1'-binaphthyl 

Relevant articles and documents

Mechanism of one oxygen atom transfer from oxo (salen) manganese(V) complex to olefins

In the Mn-salen catalyzed asymmetric epoxidation of some olefins, non-linear relationship between reaction temperature and entioselectivity was observed. For example, the epoxidation of 1,3-cycloalkadiene with complex 3a as a catalyst showed the maximum enantioselectivity at 0°C. It was also found that the electronic nature of the aromatic substituent in the salen ligand affects enantioselectivity but its effect does not necessarily correspond to the Hammet's σ-values. Based on these new experimental results, we propose a reaction mechanism which proceeds through metallaoxetane intermediate, for one oxygen atom transfer reaction from oxo (salen) manganese(V) complex to olefins.