17454-25-0Relevant articles and documents
POLARITY AND POLARIZABILITY PARAMETER DETERMINATIONS IN COMPOUNDS CONTAINING A P-N BOND
Arbuzov, B. A.,Arshinova, R. P.,White, D. W.,Verkade, J. G.
, p. 27 - 34 (2007/10/02)
The dipole moments and polarizability ellipsoids of phosphorus-containing bonds in 2,6,7-trimethyl-4-methyl-2,6,7-triaza-1-phosphaicyclooctane (3) and its 1-oxide (4) and 1-sulfide (5) and in 2-dimethylamino-1,3,2-dioxaphosphorinane (2) have been determined from dipole moment, Kerr effect and depolarization of Rayleigh scattering measurements.The conformational rigidity of bicyclic compounds such as (3-5) as well as of several 2-oxo-2R-4,6-dimethyl-1,3,2-dioxaphosphorinanes are utilized in considering the implications of assuming that the component moments are primarily directed along the phosphoryl bond.