6362-89-6

Basic information

• Product Name: 2-chloro-1,3,2-dioxaphosphinane
• Synonyms: 1,3,2-dioxaphosphorinane, 2-chloro-; 2-Chloro-1,3,2-dioxaphosphinane
• CAS NO: 6362-89-6
• Molecular Formula: C₃H₆ClO₂P
• Molecular Weight: 140.5053
• Mol File: 6362-89-6.mol
• Article Data: 3

Chemical Properties

• Boiling Point: 144.045°C at 760 mmHg
• Flash Point: 40.918°C
• Vapor Pressure: 6.522mmHg at 25°C
• CAS DataBase Reference: 2-chloro-1,3,2-dioxaphosphinane(CAS DataBase Reference)
• NIST Chemistry Reference: 2-chloro-1,3,2-dioxaphosphinane(6362-89-6)
• EPA Substance Registry System: 2-chloro-1,3,2-dioxaphosphinane(6362-89-6)

Safety Data

• Hazardous Substances Data: 6362-89-6(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 176172-29-5 1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one 
• 504-63-2 trimethyleneglycol 

Downstream Products

• 224056-38-6 biphenyl-2,2'-diyl di(trimethylene phosphite) 
• 1323951-97-8 3,5-bis(2-thiono-1,3,2-dioxaphosphorinan-2-yloxy)phenol 
• 75-77-4 chloro-trimethyl-silane 
• 176172-29-5 1-[1,3,2]Dioxaphosphinan-2-yl-pyrrolidin-2-one 
• 91117-93-0 2,2'-(o-phenyldioxy)-1,3,2-dioxaphosphorinane-1',3',2'-dioxaphosphorinane 
• 176172-41-1 2-(3,3-dimethyl-2-oxo-4-phenylazetidin-1-yl)-1,3,2-dioxaphosphorinane 
• 188903-34-6 m-bis(1,3,2λ³-dioxaphosphorin-2-yloxy)benzene 
• 136263-03-1 2-(2-phenylethynyl)-1,3,2-dioxaphosphorinane 
• 18476-18-1 2,2'-(1,3-propanedioxy)-4,5-benzo-1,3,2-dioxaphospholane-4',5'-benzo-1',3',2'-dioxaphospholane 
• 17454-25-0 2-(dimethylamino)-1,3,2-dioxaphosphorinane 
• 52463-56-6 (2-oxo-3-phenyl-2λ⁵-[1,3,2]oxazaphosphinan-2-yl)-phenyl-amine 
• 67347-96-0 2,3-diphenyl-10λ⁵-spiro[benzo[d][1,3,2]oxazaphospholo[2,3-b][1,3,2]oxazaphosphole-10,2'-[1,3,2]dioxaphosphinane] 
• 60197-03-7 2-(diphenylamino)-1,3,2-dioxaphosphorinane 
• 113977-43-8 2-benzyloxy-1,3,2-dioxaphosphorinane 

Relevant articles and documents

N-Phosphorylated lactams 2. Reversible phosphorylation of silyllactams

The phosphorylation of N-trimethylsilyllactams by phosphorus(III) acid chlorides results in corresponding N-phosphinolactams in high yields. The derivatives thus obtained have been used in the synthesis of N-phosphoryl- and N-thiophosphoryllactams. The reversibility of the reaction of phosphinolactams has been established. - Keywords: N-trimethylsilyllactams; reversible phosphorylation; N-phosphoryllactams, synthesis.

INVESTIGATIONS IN THE SYSTEM PHOSPHORUS TRICHLORIDE / 1,3-PROPANEDIOL

The reaction of phosphorus trichloride and 1,3-propanediol was reinvestigated.Besides 2-chloro-1,3,2-dioxaphosphorinane 1 3-chloropropyl-dichlorophosphite 2 was formed.Compound 1 and 2 were fluorinated to give the corresponding phosphorinane 3 and the phosphite 4, respectively.Proton NMR spectra were recorded at 360.08 MHz and simulated for 1 and 3.The 4-H and 6-H signals were treated not as first order but as AA'XX' systems.