On the stereochemistry of aryl C-glycosides: Unusual behavior of bis-TBDPS protected aryl C-olivosides

DOI: 10.1016/0040-4039(95)02227-9

Source and publish data:

Tetrahedron Letters p. 663 - 666 (1996)

Update date:2022-08-05

Topics:

Authors:

Hosoya, Takamitsu

Ohashi, Yoriko

Matsumoto, Takashi

Suzuki, Keisuke

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Article abstract of DOI:10.1016/0040-4039(95)02227-9

A D-olivosyl donor in which the C(3) and C(4) hydroxyls are both protected by an extremely bulky group, t-BuPh₂Si, undergoes aryl C-glycosidation in an α-selective manner, and the product configuration remains unchanged under various Lewis acid

Full text of DOI:10.1016/0040-4039(95)02227-9

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