174851-16-2Relevant academic research and scientific papers
Tin(IV) enolates from allylic O-stannyl ketyls: reactions with alkyl halides and HMPA
Enholm, Eric J.,Whitley, Paul E.
, p. 559 - 562 (1996)
The mild free radical reaction of an α,β-unsaturated ketone and tributyltin radical produced a resonance-stabilized allylic O-stannyl ketyl intermediate. A subsequent hydrogen atom transfer produced a tin(IV) enolate which reacts readily with activated halides and HMPA to provide a useful and mild alternative to analogues Li-NH3 alkylations.
