
Tetrahedron Letters p. 559 - 562 (1996)
Update date:2022-08-06
Topics:
Enholm, Eric J.
Whitley, Paul E.
The mild free radical reaction of an α,β-unsaturated ketone and tributyltin radical produced a resonance-stabilized allylic O-stannyl ketyl intermediate. A subsequent hydrogen atom transfer produced a tin(IV) enolate which reacts readily with activated halides and HMPA to provide a useful and mild alternative to analogues Li-NH3 alkylations.
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