174967-14-7

Basic information

• Product Name: (C₅H₅)Ru(C₅H₄C_.tplbond.CC₆H₄OMe-p)
• CAS NO: 174967-14-7
• Molecular Weight: 361.405
• Mol File: 174967-14-7.mol

Chemical Properties

• CAS DataBase Reference: (C₅H₅)Ru(C₅H₄C_.tplbond.CC₆H₄OMe-p)(CAS DataBase Reference)
• NIST Chemistry Reference: (C₅H₅)Ru(C₅H₄C_.tplbond.CC₆H₄OMe-p)(174967-14-7)
• EPA Substance Registry System: (C₅H₅)Ru(C₅H₄C_.tplbond.CC₆H₄OMe-p)(174967-14-7)

Safety Data

• Hazardous Substances Data: 174967-14-7(Hazardous Substances Data)

Upstream product

• 174967-15-8 cis-Pt(C_.tplbond.ruthenocenyl)(C₆H₄OMe-p)(1,2-bis(diphenylphosphino)ethane) 
• 7553-56-2 iodine 
• 60751-06-6 [(PPh₃)2Pd(I)(4-C₆H₄OCH₃)] 
• 14104-20-2 silver tetrafluoroborate 

Relevant articles and documents

Preparation and some properties of Pt(II) ruthenocenylacetylide complexes

Ruthenocenylacetylene reacted with trans-PtI(C6H4X-p)(PPh3)2 (X = H, Me, OMe, Cl or CO2Me) in the presence of CuI in diethylamine-CH2Cl2 to give the Pt(II) ruthenocenylacetylide complexes, trans-Pt(C=CRc) (C6H4X-p)(PPh3)2 with a good yield. Similarly, cis-Pt(C=CRc)(C6H4OMe-p)(dppe) was prepared. The structure of trans-Pt(C=CRc)(C6H4CO2Et-p)(PPh3)2 was determined by single-crystal X-ray diffraction. No reaction of the trans isomers with DDQ or AgBF4 took place, while the cis isomer was oxidized with AgBF4 to give the coupling products RcC=CC6H5OMe-p with a low yield. The oxidation of the cis isomer with iodine occurred on the Pt atom to afford p-MeOC6H4I and PtI2(dppe) as the main products.