17530-84-6

Usage

Structure

A benzene ring with a nitro group attached to the 1 position, and a phenylsulfinylmethyl group attached to the 4 position.

Functional groups

Nitro group, phenylsulfinylmethyl group.

Type of compound

Nitro compound with a benzene ring.

Potential uses

Organic synthesis, building block for the construction of more complex molecules, and possible applications in the pharmaceutical industry for the development of new drugs.

Upstream product

• 7703-38-0 4-nitrobenzylphenyl sulfide 
• 7205-94-9 chloromethyl phenyl sulfoxide 
• 98-95-3 nitrobenzene 
• 28715-70-0 methoxy-phenyl-sulfane 
• 100-11-8 1-bromomethyl-4-nitro-benzene 
• 100-14-1 4-nitrobenzyl chloride 
• 108-98-5 thiophenol 
• 6099-23-6 1-(phenylsulfinyl)acetophenone 
• 16222-10-9 1-phenyl-2-(phenylthio)ethanone 

Downstream Products

• 7703-38-0 4-nitrobenzylphenyl sulfide 
• 34063-53-1 p-nitrobenzyl phenyl sulfone 

Relevant academic research and scientific papers

Electronic and Steric Effects in Oxidations by Isoalloxazine 4a-Hydroperoxydes

The reactivity of H5-ethyl-N10-(2,6-dimethylphenyl)-4a-hydroperoxy-N3-methylisoalloxazine (2a) with para-substituted thioanisoles, alkyl phenyl sulfides, dialkyl sulfides, and benzylbutylamines has been determined.The tran

Synthesis, spectral characterization, crystal structure and catalytic activity of a novel dioxomolybdenum Schiff base complex containing 4-aminobenzhydrazone ligand: A combined experimental and theoretical study

A novel dioxomolybdenum Schiff base complex, [MoO2(L)(H2O)], was synthesized by the reaction of MoO2(acac)2 and an ONO donor Schiff base ligand (H2L: (E)-4-amino-N'-(3-ethoxy-2-hydroxybenzylidene)benz

Novel dioxomolybdenum complexes containing ONO-tridentate Schiff base ligands derived from 4-aminobenzohydrazide: synthesis, spectral characterization, and application as efficient homogeneous catalysts for selective sulfoxidation

Novel dioxomolybdenum Schiff base complexes, [MoO2(Ln)(CH3OH)], were synthesized by the reaction of MoO2(acac)2 and ONO donor Schiff base ligands (H2Ln) derived by the condensati

Modification of magnetic nanoparticles surface by oxovanadium(V) complex as a highly efficient heterogeneous nanocatalyst for the green sulfoxidation of sulfides

The present study describes the synthesis of a new nanomagnetic-supported oxovanadium(V) complex with the tridentate Schiff base ligand derived from the condensation reaction between 5-bromosalicylaldehyde and nicotinic acid hydrazide. The supported compl

Molybdenum(VI) complexes with tridentate Schiff base ligands derived from isoniazid as catalysts for the oxidation of sulfides: synthesis, X-ray crystal structure determination and spectral characterization

Two new complexes, including [MoO2(L1)(CH3OH)] and [MoO2(L2)(CH3OH)], with tridentate ONO–donor Schiff base ligands (H2L1: (E)-N'-(2-hydroxy-3-methoxybenzylidene)isoni

Experimental and theoretical studies of new dioxomolybdenum complex: Synthesis, characterization and application as an efficient homogeneous catalyst for the selective sulfoxidation

A new dioxomolybdenum(VI) complex with tridentate ONO-donor Schiff base ligand derived from isoniazid has been synthesized and characterized by elemental analyses, FT-IR and 1H NMR, and its solid state structure was confirmed by single crystal

Fe3O4?BNPs?SiO2-SO3H as a highly chemoselective heterogeneous magnetic nanocatalyst for the oxidation of sulfides to sulfoxides or sulfones

To achieve green chemistry goals and also to reduce the cost of catalysts as well as to avoid producing toxic wastes and show the importance of separation and recycling of catalysts from the reaction medium, in this work, we describe the preparation and characterization of magnetic acidic boehmite nanoparticles as a heterogeneous catalyst, which is called Fe3O4?BNPs?SiO2-SO3H. This catalyst works efficiently in the selective oxidation of sulfides to sulfoxides or sulfones in the presence of H2O2 as a green oxidant. It can easily be separated from the reaction medium by using an external magnet and it was recycled 6 times without loss of magnetic catalytic properties.

A route to benzylic arylsulfoxides from β-ketosulfoxides

The K2CO3-mediated benzylation of β-ketosulfoxides 4 with 2.0?equiv of benzylic halides 5 affords benzylic arylsulfoxides 6 in moderate yields along with trace amounts of chalcones 7. The products 6 are assumed to form in situ intermediates of sulfenate anions from β-ketosulfoxides which are commonly involved in carbon–sulfur bond formation. A plausible mechanism has been proposed.

Tetrabutylammonium tribromide impregnated MCM-48 as a heterogeneous catalyst for selective oxidation of sulfides

We report here tetrabutylammonium tribromide supported on MCM-48 as a highly efficient heterogeneous catalyst for the selective oxidation of sulfides, in ethanolic medium using hydrogen peroxide as an oxidant. The aforementioned oxidation reactions were found to proceed rapidly (20 min) and in good yield (85-99%) (17 examples). The oxidation products were characterized by 1H NMR, 13C NMR and elemental analysis. The catalytic properties were analysed by TEM, XRD and BET-surface area measurement. No over-oxidation of the substrates was observed (analysed by GC), and the catalyst was effectively recycled for five consecutive cycles without any significant loss in its catalytic activity.

Nickel(II), copper(II), and cobalt(II) complexes derived from a new unsymmetrical ONS donor schiff base ligand: Synthesis, characterization, crystal structure, and catalytic activities

A series of Ni(II), Cu(II), and Co(II) complexes, ML2, of a new thioether containing ONS donors have been synthesized, where L = deprotonated Schiff base. The analytical, spectral (FTIR,1H NMR, UV–vis), conductivity, and magnetic stu