28715-70-0

Usage

Uses

Used in Chemical Production:
(Methoxysulfanyl)benzene is used as a solvent for the production of various chemical compounds. Its ability to dissolve a wide range of substances makes it a valuable asset in the chemical industry.
Used in Fragrance and Flavor Industry:
(Methoxysulfanyl)benzene is used as a key component in the fragrance and flavor industry. Its sweet, pleasant aroma contributes to the creation of various scents and flavors in products such as perfumes, candles, and food additives.
Used in Pharmaceutical Synthesis:
(Methoxysulfanyl)benzene is used as a starting material in the synthesis of pharmaceuticals. Its unique chemical structure allows for the development of new and effective medications.
Used in Dye and Perfume Production:
(Methoxysulfanyl)benzene is used as a precursor in the production of dyes and perfumes. Its aromatic nature and versatility make it an essential component in creating vibrant colors and captivating scents.
Used in Organic Chemistry:
(Methoxysulfanyl)benzene is used as a valuable building block in organic chemistry. Its methoxy substituent allows for the creation of various organic compounds, making it an important precursor in the synthesis of numerous substances.
Safety Precautions:
It is important to handle (methoxysulfanyl)benzene with caution, as it can be harmful if inhaled or ingested and can cause irritation to the skin and eyes. Proper safety measures should be taken when working with (methoxysulfanyl)benzene to minimize potential health risks.

Upstream product

• 124-41-4 sodium methylate 
• 931-59-9 benzenesulfenyl chloride 
• 4972-29-6 benzenesulphinyl chloride 
• 882-33-7 diphenyldisulfane 
• 67-56-1 methanol 
• 100-68-5 methyl-phenyl-thioether 
• 20057-88-9 diphenyl trisulfide 
• 53144-50-6 diphenyl tetrasulfide 
• 28074-23-9 phenylsulfenyl bromide 
• 108-98-5 thiophenol 

Downstream Products

• 67-56-1 methanol 
• 139-66-2 diphenyl sulfide 
• 945-51-7 1,1'-sulfinylbisbenzene 
• 24210-19-3 methyl (2S)-3-methyl-[(benzyloxy)carbonylamino]butanoate 
• 670-98-4 methyl benzenesulfinate 
• 24380-82-3 n-Propyl-benzolsulfenamid 
• 34066-26-7 sec-Butyl-benzolsulfenamid 
• 24380-79-8 S-phenyl-N,N-dimethylsulfenamide 
• 34723-51-8 Trimethylsilyl-methyl-benzolsulfenamid 
• 28968-93-6 N-sulfinyl-phenylthioamine 
• 24398-49-0 N-methyl-N-(phenylthio)benzenesulfenamide 
• 34690-95-4 N-isobutyl phenylsulphenamide 
• 24380-80-1 N-ethyl-S-phenylsulfenamide 
• 34690-94-3 N-(phenylthio)-N-(iso-propyl)amine 

Relevant academic research and scientific papers

Formation, stability, and reactivity of a mononuclear nonheme oxoiron(IV) complex in aqueous solution

A mononuclear nonheme oxoiron(IV) complex bearing a pentadentate N5 ligand was prepared in aqueous solution; the pH dependence of its stability and reactivities was reported along with the mechanistic details of sulfide oxidation by the oxoiron(IV) species. The Royal Society of Chemistry 2005.

Unified Approach to Benzo[ d]thiazol-2-yl-Sulfonamides

In this paper, we report a unified approach to N-substituted and N,N-disubstituted benzothiazole (BT) sulfonamides. Our approach to BT-sulfonamides starts from simple commercially available building blocks (benzo[d]thiazole-2-thiol and primary and secondary amines) that are connected via (a) a S oxidation/S-N coupling approach, (b) a S-N coupling/S-oxidation sequence, or via (c) a S-oxidation/S-F bond formation/SuFEx approach. The labile N-H bond in N-monoalkylated BT-sulfonamides (pKa (BTSO2N(H)Bn) = 3.34 ± 0.05) further allowed us to develop a simple weak base-promoted N-alkylation method and a stereoselective microwave-promoted Fukuyama-Mitsunobu reaction. N-Alkyl-N-aryl BT-sulfonamides were accessed with the help of the Chan-Lam coupling reaction. Developed methods were further used in stereo and chemoselective transformations of podophyllotoxin and several amino alcohols.

Hammett Correlations in the Photosensitized Oxidation of 4-Substituted Thioanisoles

Singlet oxygen is quenched by a series of 4-substituted thioanisoles (methoxy to nitro), with rate constant kt = 7 × 104 to 7 × 106 M-1 s-1, close to the value observed for the myoglobin-catalyzed sulfoxidation of the same sulfides. Correlations with σ (ρ = -1.97) and with Eox (slope -3.9 V-1) are evidence for an electrophilic mechanism. In methanol sulfoxides are formed (85%) via an intermediate quenched by diphenyl sulfoxide; competing minor paths lead to arylthiols, arylsulfenic acid, and aryl sulfoxides. In aprotic solvents, the sulfoxidation is quite sluggish, but carboxylic acids (mostly ≤0.1 M) enhance the rate by a factor of > 100. The protonated persulfoxide is formed in this case and acts as an electrophile with sulfides, again with a rate constant correlating with σ (ρ = -1.78).

Model Reaction of Self-Condensation of Sulfenic Acids. Kinetic Investigation for the Reaction of Methyl Benzenesulfenate with trans-Decalin-9-sulfenic Acid and 2-Methyl-2-propanesulfenic Acid

Reaction of 2-methyl-2-propanesulfenic acid (1) with methyl arenesulfenates (2) gave S-aryl 2-methyl-2-propanethiosulfinates quantitatively, and kinetic investigation was carried out.Second-order rate dependence (first-order in methyl benzenesulfenate (2a

THE THIO-ARBUZOV-REACTION. PART 9. SYNTHESIS OF DISULFINATES AND DISULFOXIDES BY ''DOUBLE'' THIO-ARBUZOV-REACTIONS OF ALKOXYSULFANES WITH ω,ω'-BIS(BROMOMETHYL)-ARENES AND -ALKENES

Thio-ARBUZOV-Reactions of dialkyl sulfoxylates and methyl benzenesulfenate, respectively, with several aromatic and aliphatic ω,ω'-bis(bromomethyl)arenes and -alkenes result in formation of new disulfinyl derivatives, i.e. disulfinates and disulfoxides.Ei