175469-08-6

Basic information

• Product Name: N-benzyl,N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-2-aminoacetamide
• CAS NO: 175469-08-6
• Molecular Weight: 430.59
• Mol File: 175469-08-6.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: N-benzyl,N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-2-aminoacetamide(CAS DataBase Reference)
• NIST Chemistry Reference: N-benzyl,N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-2-aminoacetamide(175469-08-6)
• EPA Substance Registry System: N-benzyl,N-(5,5-dimethyl-3-oxo-cyclohex-1-enyl)-2-aminoacetamide(175469-08-6)

Safety Data

• Hazardous Substances Data: 175469-08-6(Hazardous Substances Data)

Upstream product

• 100-46-9 benzylamine 
• 889-31-6 5,5-dimethyl-3-benzylamino-2-cyclohexen-1-one 
• 3471-13-4 dimedone 
• 115914-08-4 (S)-N-(1-phenylethyl)prop-2-en-1-amine 

Relevant articles and documents

Photorearrangement of N-alkanoyl β-enaminones. Application to the synthesis of α-amino-β,γ-unsaturated acid derivatives

The irradiation of N-alkanoyll-β-enaminones lead to the formation of spiranic β-lactams which undergo C-N bond cleavage during chromatography on alumina giving cycloalkenones functionalized at position 3. This new rearrangement has been applied to the synthesis of α-amino-β,γ-unsaturated amides in one step and gives convenient yields.