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Usage

Uses

Used in Flavor and Fragrance Industry:
(Z)-1-Acetoxy-1-heptene is used as a flavoring agent and fragrance ingredient for its distinctive fruity scent. It adds a pleasant aroma to various consumer products, enhancing their appeal and sensory experience.
Used in Chemical Synthesis:
(Z)-1-Acetoxy-1-heptene serves as a key intermediate in the synthesis of other chemicals and pharmaceuticals. Its unique chemical structure allows for further reactions and modifications, contributing to the development of new and innovative products in the chemical and pharmaceutical industries.
Used in Pharmaceutical Industry:
Although not explicitly mentioned in the provided materials, given its role in chemical synthesis, (Z)-1-Acetoxy-1-heptene may also be utilized in the development of pharmaceutical compounds. Its potential applications in this industry could include the creation of new drugs or the enhancement of existing medications.

Upstream product

• 3240-34-4 [bis(acetoxy)iodo]benzene 
• 57404-76-9 trans-1-heptenylboronic acid 
• 628-71-7 1-Heptyne 
• 64-19-7 acetic acid 
• 111-71-7 heptanal 
• 108-24-7 acetic anhydride 

Downstream Products

• 749885-73-2 Acetic acid (1S,2R)-2-pentyl-cyclopropyl ester 
• 749885-73-2 Acetic acid (1S,2R)-2-pentyl-cyclopropyl ester 

Relevant academic research and scientific papers

InCl3/Me3SiBr-catalyzed direct coupling between silyl ethers and enol acetates

A combined Lewis acid catalyst of InCl3 and Me3SiBr promoted the direct use of enol acetates in the coupling with low-reactive silyl ethers, in which functional groups including ketones and aldehydes survived. Sterically hindered silyl ethers such as ROSiEt3, ROSiPh3, ROSit-BuMe2, and ROSii-Pr3 were also applicable.

Ligand-controlled regio- and stereoselective addition of carboxylic acids onto terminal alkynes catalyzed by carbonylruthenium(0) complexes

The addition of carboxylic acids onto terminal alkynes was catalyzed by mononuclear ruthenium(0) complexes to give enol esters in high yields. By using ligands with different electronic properties, product selectivity was achieved. E-enol esters were preferentially produced when tricarbonyl(η4- diene)ruthenium complexes were used; while geminal enol esters were produced when tricarbonylbis(phosphane)ruthenium complexes were used. Product selectivity is a major problem in transition metal-catalyzed hydrocarboxylation reactions. In this paper we report the ability of Ru(CO)3L2 (where L is a 2 e-donor) to catalyze the addition of variouscarboxylic acids onto terminal alkynes. A direct relationship between the regioselectivity of the product and the electronic property of the catalysis metal centre was observed.

Kinetic Enzymatic Resolution of Cyclopropane Derivatives

The kinetic enzymatic resolution of various cyclopropane derivatives was systematically investigated. The study focused on synthetically useful cyclopropylmethanols (e.g., 18a/j or 19a/j) as well as some rarely investigated cyclopropanols (e.g., 24/25 or 27). The combination of enantioselective catalytic or diastereoselective synthesis of enantiomerically enriched compounds with enzymatic approaches ultimately led to the most convenient route to enantiomerically pure starting materials. Again, this was especially proven for the synthesis of cyclopropanols 18a/j and 19a/j. Key to the successful investigation was to rigorously establish an analytical tool for the analysis of enantiomeric composition of reaction mixtures.