175789-75-0Relevant academic research and scientific papers
One-pot, three-component synthesis of 1,4,5-trisubstituted 1,2,3-triazoles starting from primary alcohols
Jin, Guanyi,Zhang, Jian,Fu, Dan,Wu, Jingjing,Cao, Song
supporting information, p. 5446 - 5449 (2012/10/30)
A novel, one-pot, three-component approach for the synthesis of 1,4,5-trisubstituted 1,2,3-triazoles through the cycloaddition of a wide range of primary alcohols with sodium azide and active methylene ketones in the presence of N-(p-toluenesulfonyl)imidazole, tetrabutylammonium iodide, and triethylamine in DMF/DMSO has been developed.
REACTION DU METHYLAZIDE AVEC DES OLEFINES CINNAMIQUES, CROTONIQUES ET ACRYLIQUES. ETUDE DES COMPOSES OBTENUS
Hetet, G. Le,Benhaoua, H.,Carrie, R.
, p. 189 - 204 (2007/10/03)
Methylazide reacts with the title olefines and gives expected 1,2,3-triazolines in equilibrium with corresponding amino dizao compounds.Because this equilibrium, E and Z olefines gives the same result, and the addition do not seem stereospecific.Thermolys
REACTIONS DES METHYLAZIDE ET PHENYLAZIDE AVEC QUELQUES ALCYNES ET OLEFINES α-NITREES. SYNTHESE REGIOSPECIFIQUE DES 1,2,3 TRIAZOLES
Piet, J. C.,Hetet, G. Le,Cailleux, P.,Benhaoua, H.,Carrie, R.
, p. 33 - 44 (2007/10/03)
The reactions of alkynes and α-nitro-olefines with methylazide and phenylazide was studied.In contrast to known reactions with alkynes which are non-regioselective, methylazide and phenylazide react regiospecifically with α-nitro-olefines and give only one type of triazole after elimination of HNO2.These reactions are very useful synthetic approaches to 1,2,3 triazoles.
