175854-88-3

Basic information

• Product Name: C₁₁H₁₈N₂O₂Si
• Synonyms: C₁₁H₁₈N₂O₂Si
• CAS NO: 175854-88-3
• Molecular Weight: 238.362
• Mol File: 175854-88-3.mol
• Article Data: 1

Chemical Properties

• CAS DataBase Reference: C₁₁H₁₈N₂O₂Si(CAS DataBase Reference)
• NIST Chemistry Reference: C₁₁H₁₈N₂O₂Si(175854-88-3)
• EPA Substance Registry System: C₁₁H₁₈N₂O₂Si(175854-88-3)

Safety Data

• Hazardous Substances Data: 175854-88-3(Hazardous Substances Data)

Upstream product

• 83600-07-1 1-nitro-2-phenylaminoethane 
• 10416-58-7 N,N-bis(trimethylsilyl)acetamide 

Downstream Products

• 3768-55-6 N-trimethylsilylaniline 

Relevant articles and documents

Trimethylsilyl Nitronates Derived from 2-Substituted Nitroethanes in δ-Elimination Reactions

Silylation of β-substituted nitroethanes XCH2CH2NO2 (X=Cl or OCOCH3) with conventional silylating agents yields corresponding trimethylsilyl nitronates which undergo δ-elimination of nitroethylene under the reaction conditions.Stable silyl nitronates containing one or two trimethylsilyl groups were isolated in the silylation of C6H5NHCH2CH2NO2. 1,3-Dipolar cycloaddition of the nitronates to methoxide ion results in formation of 5-methoxycarbonyl-3-phenylaminomethyl(or 3-N-trimethylsilylphenylaminomethyl)-3-trimethylsiloxyisoxazolidines.Thermolysis of the latter affords 5-methoxycarbonyl-2-isoxazoline.