176167-48-9

Upstream product

• 151669-30-6 ethyl 2,3-di-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 100-39-0 benzyl bromide 
• 176167-47-8 ethyl 6-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 74-88-4 methyl iodide 

Downstream Products

• 176167-61-6 4-[2-(benzyloxycarbonylamino)ethyl]phenyl 2,4-di-O-methyl-3-O-{4-O-benzyl-2-O-methyl-3-O-[4-O-acetyl-2-O-methyl-3-O-(2,3,6-tri-O-benzyl-4-O-methyl-α-D-mannopyranosyl)-α-L-fucopyranosyl]-α-L-rhamnopyranosyl}-α-L-rhamnopyranoside 
• 176167-65-0 4-[2-(benzyloxycarbonylamino)ethyl]phenyl 2,4-di-O-methyl-3-O-{4-O-benzyl-2-O-methyl-3-O-[4-O-acetyl-2-O-methyl-3-O-(3,6-di-O-benzyl-2-O-chloroacetyl-4-O-methyl-α-D-mannopyranosyl)-α-L-fucopyranosyl]-α-L-rhamnopyranosyl}-α-L-rhamnopyranoside 
• 176167-76-3 methyl 4-O-acetyl-3-O-[3,6-di-O-benzyl-2-O-(2-dibromomethyl)benzoyl-4-O-methyl-α-D-mannopyranosyl]-2-O-methyl-α-L-fucopyranoside 
• 176167-70-7 ethyl 3,6-di-O-benzyl-2-O-(2-dibromomethyl)benzoyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-69-4 ethyl 2-O-benzoyl-3,6-di-O-benzyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-50-3 ethyl 2,3,6-tri-O-benzyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-64-9 ethyl 3,6-di-O-benzyl-2-O-chloroacetyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-68-3 ethyl 2-O-acetyl-3,6-di-O-benzyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-63-8 ethyl 3,6-di-O-benzyl-4-O-methyl-1-thio-D-mannopyranoside 

Relevant academic research and scientific papers

Iodonium ion-assisted synthesis of tetrameric fragments corresponding to the cell wall phenolic glycolipids of Mycobacterium kansasii serovars II and IV

The spacer-containing tetramers 3 and 4, derivatives of the phenolic glycolipids of Mycobacterium kansasii serovars II and IV were prepared by iodonium ion-mediated mannosylation of trimeric acceptor 4-[2-(benzyloxycarbonylamino)ethyl]phenyl 2,4-di-O-methyl-3-O-[4-O-benzyl-2-O-methyl-3-O-(4-O-acetyl-2-O-methyl- α-L-fucopyranosyl)-α-L-rhamnopyranosyl]-α-L-rhamnopyranoside (2) with ethyl 1-thio-D-mannopyranoside donors 7, 13 and 24. In addition, the glycosylating properties of donors 7, 13, 24, 29-31, each containing a different protective group at position 2, were examined by executing condensations with model acceptor 18(L) and its enantiomer 18(D).