176167-76-3

Upstream product

• 176167-70-7 ethyl 3,6-di-O-benzyl-2-O-(2-dibromomethyl)benzoyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176039-85-3 methyl 4-O-acetyl-2-O-methyl-α-L-fucopyranoside 
• 99603-80-2 methyl 2-O-methyl-α-L-fucose 
• 73407-51-9 o-di-bromomethyl-benzoyl chloride 
• 100-39-0 benzyl bromide 
• 42822-20-8 methyl 3,4-O-isopropylidene-2-O-methyl-α-L-fucopyranoside 
• 151669-30-6 ethyl 2,3-di-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 176167-49-0 ethyl 6-O-benzyl-4-O-methyl-1-thio-α-D-mannopyranoside 
• 176167-47-8 ethyl 6-O-benzyl-2,3-O-isopropylidene-1-thio-α-D-mannopyranoside 
• 176167-48-9 (3aS,4R,6R,7R,7aS)-6-Benzyloxymethyl-4-ethylsulfanyl-7-methoxy-2,2-dimethyl-tetrahydro-[1,3]dioxolo[4,5-c]pyran 
• 24577-96-6 methyl 3,4-di-O-isopropylidene-α-L-fucopyranoside 
• 176167-63-8 ethyl 3,6-di-O-benzyl-4-O-methyl-1-thio-D-mannopyranoside 

Relevant academic research and scientific papers

Iodonium ion-assisted synthesis of tetrameric fragments corresponding to the cell wall phenolic glycolipids of Mycobacterium kansasii serovars II and IV

The spacer-containing tetramers 3 and 4, derivatives of the phenolic glycolipids of Mycobacterium kansasii serovars II and IV were prepared by iodonium ion-mediated mannosylation of trimeric acceptor 4-[2-(benzyloxycarbonylamino)ethyl]phenyl 2,4-di-O-methyl-3-O-[4-O-benzyl-2-O-methyl-3-O-(4-O-acetyl-2-O-methyl- α-L-fucopyranosyl)-α-L-rhamnopyranosyl]-α-L-rhamnopyranoside (2) with ethyl 1-thio-D-mannopyranoside donors 7, 13 and 24. In addition, the glycosylating properties of donors 7, 13, 24, 29-31, each containing a different protective group at position 2, were examined by executing condensations with model acceptor 18(L) and its enantiomer 18(D).