17626-86-7

Basic information

• Product Name: Benzothiazole, 2-(1-methylethyl)- (9CI)
• Synonyms: Benzothiazole, 2-(1-methylethyl)- (9CI);Benzothiazole, 2-(1-Methylethyl)-
• CAS NO: 17626-86-7
• Molecular Formula: C₁₀H₁₁NS
• Molecular Weight: 177.26604
• Product Categories: BENZOTHIAZOLE
• Mol File: 17626-86-7.mol
• Article Data: 46

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Benzothiazole, 2-(1-methylethyl)- (9CI)(CAS DataBase Reference)
• NIST Chemistry Reference: Benzothiazole, 2-(1-methylethyl)- (9CI)(17626-86-7)
• EPA Substance Registry System: Benzothiazole, 2-(1-methylethyl)- (9CI)(17626-86-7)

Safety Data

• Hazardous Substances Data: 17626-86-7(Hazardous Substances Data)

Upstream product

• 95-16-9 1,3-Benzothiazole 
• 75-30-9 2-iodo-propane 
• 64345-00-2 2-(phenylsulfonyl)benzo[d]thiazole 
• 30615-19-1 isopropylmercury(II) chloride 
• 106636-79-7 benzothiazole trifluoroacetate 
• 137-07-5 2-amino-benzenethiol 
• 75755-45-2 N,2-dimethyl-N-phenylpropanethioamide 
• 1539-32-8 4-isopropyl-2,6-dimethyl-1,4-dihydro-pyridine-3,5-dicarboxylic acid diethyl ester 
• 1123-99-5 2-iodobenzothiazole 
• 98370-54-8 zinc 2-aminobenzenethiolate 
• 79-30-1 isobutyryl chloride 
• 4406-41-1 N-phenylisobutyramide 
• 62-53-3 aniline 
• 78-82-0 Isobutyronitrile 

Relevant articles and documents

Mn(II)-catalyzed C-H alkylation of imidazopyridines and N-heteroarenes via decarbonylative and cross-dehydrogenative coupling

A Mn(II)-catalyzed efficient C-H alkylation of imidazoheterocycles and N-heteroarenes with aliphatic aldehydes has been developed via oxidative decarbonylation. Other alkylating agents such as cyclic alkanes, ethers, and alcohols also coupled with N-heteroarenes through cross-dehydrogenative coupling. Regioselectively C5-alkylated imidazoheterocycles were synthesized in good yields. Experimental results show that radical pathway might be involved in this reaction.

Ultrasound-assisted efficient and green synthesis of 2-substituted benzothiazoles under solvent-free condition using recyclable sulfated tungstate

Sulfated tungstate catalyzed an efficient and ecofriendly protocol has been described for the synthesis of 2-substituted benzothiazoles. The corresponding benzothiazoles were obtained using a condensation reaction of 2-aminothiophenol with various aldehydes under ultrasound irradiation at room temperature. Various functional groups on the 2-aminothiophenol as well as on the aldehydes were tolerated to provide 2-substituted benzothiazoles derivatives in excellent yields. The faster reaction rate, solvent-free or mild reaction conditions, wide functional group compatibility, excellent yields, easy work-up procedure, and excellent catalyst recyclability are the advantages of this protocol. These advantages make this process more practicable, cost-effective, and environmentally benign.

Visible-Light Carbon Nitride-Catalyzed Aerobic Cyclization of Thiobenzanilides under Ambient Air Conditions

A metal-free heterogeneous photocatalysis has been developed for the synthesis of benzothiazoles via intramolecular C-H functionalization/C-S bond formation of thiobenzanilides by inexpensive graphitic carbon nitride (g-C3N4) under visible-light irradiation. This reaction provides access to a broad range of 2-substituted benzothiazoles in high yields under an air atmosphere at room temperature without addition of a strong base or organic oxidizing reagents. In addition, the catalyst was found to be stable and reusable after five reaction cycles.