176446-53-0Relevant academic research and scientific papers
Ligand Non-innocence and Single Molecular Spintronic Properties of AgII Dibenzocorrole Radical on Ag(111)
Xu, Jialiang,Zhu, Li,Gao, Hu,Li, Chenhong,Zhu, Meng-Jiao,Jia, Zhen-Yu,Zhu, Xin-Yang,Zhao, Yue,Li, Shao-Chun,Wu, Fan,Shen, Zhen
supporting information, p. 11702 - 11706 (2021/04/29)
A facile method for the quantitative preparation of silver dibenzo-fused corrole Ag-1 is described. In contrast to the saddle conformation resolved by single-crystal X-ray analysis for Ag-1, it adopts an unprecedented domed geometry, with up and down orientations, when adsorbed on an Ag(111) surface. Sharp Kondo resonances near Fermi level, both at the corrole ligand and the silver center were observed by cryogenic STM, with relatively high Kondo temperature (172 K), providing evidence for a non-innocent AgII-corrole.2? species. Further investigation validates that benzene ring fusion and molecule-substrate interactions play pivotal roles in enhancing Ag(4d(x2?y2))–corrole (π) orbital interactions, thereby stabilizing the open-shell singlet AgII-corrole.2? on Ag(111) surface. Moreover, this strategy used for constructing metal-free benzene-ring fused corrole ligand gives rise to inspiration of designing novel metal–corrole compound for multichannel molecular spintronics devices.
Pentaphyrins useful in the biomedical field
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Paragraph 0087; 0088, (2014/12/12)
The present disclosure relates to novel pentaphyrins, which can be used for instance in the biomedical field, or in cation or anion binding applications or for manufacturing near infrared materials.
Two-photon oxygen sensing with quantum dot-porphyrin conjugates
Lemon, Christopher M.,Karnas, Elizabeth,Bawendi, Moungi G.,Nocera, Daniel G.
supporting information, p. 10394 - 10406 (2013/10/01)
Supramolecular assemblies of a quantum dot (QD) associated to palladium(II) porphyrins have been developed to detect oxygen (pO2) in organic solvents. Palladium porphyrins are sensitive in the 0-160 Torr range, making them ideal phosphors for i
