17647-70-0

Basic information

• Product Name: aminomethyl-furaza
• Synonyms: 4-methylfurazanamine;5-oxadiazol-3-amine,4-methyl-2;aminomethyl-furaza;4-Methyl-1,2,5-oxadiazole-3-amine;4-Methylfurazan-3-amine;1,2,5-oxadiazol-3-amine, 4-methyl-;m80338;4-methyl-1,2,5-oxadiazol-3-amine(SALTDATA: FREE)
• CAS NO: 17647-70-0
• Molecular Formula: C₃H₅N₃O
• Molecular Weight: 99.0913
• Mol File: 17647-70-0.mol
• Article Data: 5

Chemical Properties

• Melting Point: 72.8-73.8 °C(Solv: chloroform (67-66-3); ligroine (8032-32-4))
• Boiling Point: 208°C at 760 mmHg
• Flash Point: 79.6°C
• Appearance: /
• Density: 1.283g/cm³
• Vapor Pressure: 0.219mmHg at 25°C
• Refractive Index: 1.528
• PKA: 1.44±0.47(Predicted)
• CAS DataBase Reference: aminomethyl-furaza(CAS DataBase Reference)
• NIST Chemistry Reference: aminomethyl-furaza(17647-70-0)
• EPA Substance Registry System: aminomethyl-furaza(17647-70-0)

Safety Data

• HazardClass: IRRITANT
• Hazardous Substances Data: 17647-70-0(Hazardous Substances Data)

Usage

General Description

Researching multiple databases and scientific resources, I've found no information or references pertaining to a chemical compound named "aminomethyl-furaza." It's possible there might be a typographical error in the name, or it could be a less common or newly discovered compound not widely discussed in accessible scientific literature. Please cross-check the name and spelling. If it's a newly analyzed compound, then details regarding its structure, properties, and potential uses may not be publicly available.

InChI:InChI=1/C3H5N3O/c1-2-3(4)6-7-5-2/h1H3,(H2,4,6)

Upstream product

• 4937-85-3 anti-1-methyl-2-aminoglyoxime 
• 31915-82-9 (Z)-2-oxopropanal oxime 
• 306-44-5 propanone 1-oxime 
• 7647-01-0 hydrogenchloride 
• 99285-92-4 3-acetyl-5-phenyl-1,2,4-oxadiazole (E)-oxime 
• 5570-27-4 4-methyl-3-nitrofuroxan 
• 141-97-9 ethyl acetoacetate 
• 17280-41-0 anti-pyruvic aldehyde 1-oxime 
• 7803-49-8 hydroxylamine 
• 7664-41-7 ammonia 
• 137890-19-8 3-(N-Hydroxycarbamimidoyl)-isoxazole-5-carboxylic acid amide 
• 137890-25-6 Isoxazole-3-carboxamidoxime 
• 1804-15-5 2-hydroxyimino-propionaldehyde oxime 

Downstream Products

• 65225-88-9 3-Acetamido-4-methylfurazan 
• 102140-71-6 3-(Benzoylamino)-4-methylfurazan 
• 63558-48-5 1-(4-methyl-furazan-3-yl)-3-phenyl-urea 
• 64821-98-3 1-(4-methyl-furazan-3-yl)-3-phenyl-thiourea 
• 32545-22-5 3-metil-4-cloroacetilaminofurazan 
• 37101-10-3 2-oximinopropionitrile 
• 77666-53-6 4-methyl-3-nitrofurazan 
• 361448-17-1 3-pentafluorobenzoylamino-4-methylfurazan 
• 473812-12-3 3-methyl-4-(pyrrol-1-yl)furazan 
• 1379659-18-3 N-([1,2,4]triazolo[4,3-b][1,2,4,5]tetrazin-6-yl)-4-methyl-1-furazan-3-amine 

Relevant articles and documents

N -Oxide-Controlled Chemoselective Reduction of Nitrofuroxans

A facile and chemoselective SnCl 2 -mediated mild reduction of regioisomeric 3- and 4-nitrofuroxans for the synthesis of aminofurazans and aminofuroxans in good yields is developed. Reduction of 4-nitrofuroxans results in the selective formation of 4-aminofuroxans, while analogous reduction of 3-nitrofuroxans affords 3-aminofurazans as a result of simultaneous reduction of the nitro group and exocyclic N-O bond.

Synthesis of 3-alkyl-4-aminofurazans

A "one-pot" method for the synthesis of 3-alkyl-4-aminofurazans from ethyl β-alkyl-β-oxopropionates was developed. The multistep process involves hydrolysis of the ester, nitrosation at the activated methylene group, and treatment of the resulting intermediate with an alkaline solution of hydroxylamine in the presence of urea.

INVESTIGATION OF THE MECHANISM OF FORMATION OF HETEROCYCLES BY NMR SPECTROSCOPY. V. 3-AMINO-4-METHYLFURAZAN

The kinetics of the reaction of hydroxyiminoacetone with hydroxylamine were studied by PMR spectroscopy.The formation of 3-amino-4-methylfurazan is a multistage process; the intermediate products are methylglyoxime, methylfurazan, α-hydroxyiminopropionitrile, and methylaminoglyoxime, and the side product is α-hydroxyiminopropionamide.