trans-{((C₆H₅)3Sn)2Ru(CO)4}

Base Information

• Chemical Name: trans-{((C₆H₅)3Sn)2Ru(CO)4}
• CAS No.: 17653-14-4
• Molecular Formula: C₄₀H₃₀O₄RuSn₂
• Molecular Weight: 913.166
• Mol file: 17653-14-4.mol

Synonyms:

Chemical Property of trans-{((C₆H₅)3Sn)2Ru(CO)4}

Chemical Property:

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

Useful:

Technology Process of trans-{((C₆H₅)3Sn)2Ru(CO)4}

There total 5 articles about trans-{((C₆H₅)3Sn)2Ru(CO)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

Ru3(CO)10(acetonitrile)2 (103257-53-0) + triphenylstannane (892-20-6) → Ru(CO)4(SnPh3)2 (17653-14-4) + HRu(CO)4(SnPh3) + Ru3(CO)10(SnPh3)2(μ-H)2 + Ru3(CO)9(SnPh3)2(μ-H)2

Guidance literature:

In hexane; (N2); HSnPh3 in hexane was added to suspn. of ruthenium complex in hexane, stirred at room temp. for 20 min; evapd. in vac., thin layer chromy. (silica gel, hexane-CH2Cl2, 4:1), elem. anal.;

DOI:10.1016/j.jorganchem.2008.08.033

Reference yield: 20.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + (C6H5)3SnS(CH2)3SSn(C6H5)3 (56535-49-0) → trans-{((C6H5)3Sn)2Ru(CO)4} (17653-14-4) + Ru2(CO)6(μ-SCH2CH2CH2S) (288141-53-7)

Guidance literature:

In tetrahydrofuran; N2; Ru compd. (0.15 mmol) and Sn compd. (0.156 mmol) refluxed in THF for3 h; evapd., chromd. (SiO2, hexane/CH2Cl2=7/3), recrystd. (hexane/CH2Cl2, 4°C), elem. anal.;

DOI:10.1016/j.ica.2009.05.011

Reference yield: 3.0%

dodecacarbonyl-triangulo-triruthenium (15243-33-1) + triphenylstannane (892-20-6) + acetonitrile (75-05-8,26809-02-9) → Ru(CO)4(SnPh3)2 (17653-14-4) + Ru3(CO)9(SnPh3)2(μ-H)2 + Ru3(CO)7(ShPh3)3(NCMe)2(μ-H)3

Guidance literature:

In dichloromethane; acetonitrile; (N2); CH3CN was added at -78°C to soln. of Ru3(CO)12 in CH2Cl2, suspn. of Me3NO*2H2O in CH3CN was added, warmed to room temp., filtered over silica gel column, soln. of HSnPh3 was added, after 20 min reaction was stopped; evapd. in vac., thin layer chromy., (silica gel, hexane-CH2Cl2, 4:1), elem. anal.;

DOI:10.1016/j.jorganchem.2008.08.033

upstream raw materials:

dodecacarbonyl-triangulo-triruthenium

triphenylstannane

acetonitrile

Ru₃(CO)10(acetonitrile)2

Refernces

• 1、 Ghosh, Shishir,Pervin, Rehana,Raha, Arun K.,Kabir, Shariff E.,Nicholson, Brian K.. "Sn-S and Ru-Ru bonds cleavage reactions between [Ph3SnS(CH2)3SSnPh3] and Ru3(CO)12: X-ray crystal structures of [Ph3SnS(CH2)3SSnPh3] and trans-[R". . p. 4226 - 4230. Retrieved 2010/01/31.