trans-{((C₆H₅)3Sn)2Ru(CO)4}

Base Information

Chemical Name:trans-{((C₆H₅)3Sn)2Ru(CO)4}
CAS No.:17653-14-4
Molecular Formula:C₄₀H₃₀O₄RuSn₂
Molecular Weight:913.166
Hs Code.:

trans-{((C<sub>6</sub>H<sub>5</sub>)3Sn)2Ru(CO)4}

Synonyms:

Suppliers and Price of trans-{((C₆H₅)3Sn)2Ru(CO)4}

Supply Marketing:

Business phase:: The product has achieved commercial mass production^*data from LookChem market partment

Manufacturers and distributors:

Manufacture/Brand
Chemicals and raw materials
Packaging
price

Total 0 raw suppliers

Chemical Property of trans-{((C₆H₅)3Sn)2Ru(CO)4}

Chemical Property:

Purity/Quality:

Safty Information:

Pictogram(s):
Hazard Codes:

MSDS Files:

Useful:

Technology Process of trans-{((C₆H₅)3Sn)2Ru(CO)4}

There total 5 articles about trans-{((C₆H₅)3Sn)2Ru(CO)4} which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 21.0%

: 103257-53-0
Ru₃(CO)10(acetonitrile)2

: 892-20-6
triphenylstannane

: 17653-14-4
Ru(CO)4(SnPh₃)2

: HRu(CO)4(SnPh₃)

: Ru3(CO)10(SnPh3)2(μ-H)2

: Ru3(CO)9(SnPh3)2(μ-H)2

Guidance literature:: In hexane; (N2); HSnPh3 in hexane was added to suspn. of ruthenium complex in hexane, stirred at room temp. for 20 min; evapd. in vac., thin layer chromy. (silica gel, hexane-CH2Cl2, 4:1), elem. anal.;
DOI:10.1016/j.jorganchem.2008.08.033

Reference yield: 20.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 56535-49-0
(C₆H₅)3SnS(CH₂)3SSn(C₆H₅)3

: 17653-14-4
trans-{((C₆H₅)3Sn)2Ru(CO)4}

: 288141-53-7
Ru2(CO)6(μ-SCH2CH2CH2S)

Guidance literature:: In tetrahydrofuran; N2; Ru compd. (0.15 mmol) and Sn compd. (0.156 mmol) refluxed in THF for3 h; evapd., chromd. (SiO2, hexane/CH2Cl2=7/3), recrystd. (hexane/CH2Cl2, 4°C), elem. anal.;
DOI:10.1016/j.ica.2009.05.011

Reference yield: 3.0%

: 15243-33-1
dodecacarbonyl-triangulo-triruthenium

: 892-20-6
triphenylstannane

: 75-05-8,26809-02-9
acetonitrile

: 17653-14-4
Ru(CO)4(SnPh₃)2

: Ru3(CO)9(SnPh3)2(μ-H)2

: Ru3(CO)7(ShPh3)3(NCMe)2(μ-H)3

Guidance literature:: In dichloromethane; acetonitrile; (N2); CH3CN was added at -78°C to soln. of Ru3(CO)12 in CH2Cl2, suspn. of Me3NO*2H2O in CH3CN was added, warmed to room temp., filtered over silica gel column, soln. of HSnPh3 was added, after 20 min reaction was stopped; evapd. in vac., thin layer chromy., (silica gel, hexane-CH2Cl2, 4:1), elem. anal.;
DOI:10.1016/j.jorganchem.2008.08.033