17729-55-4Relevant academic research and scientific papers
Synthesis of fluorescent aminophosphonates by green chemistry procedures
Ku?nierz, Anna,Chmielewska, Ewa
, p. 700 - 705 (2017)
Fluorescent aminophosphonates were obtained using optimized conditions of the microwave-stimulated Kabachnik-Fields reaction. Unfortunately, in the case of more demanding, bulky amines and aldehydes this reaction failed to give the desired products.
Radical Cation Salt-initiated Aerobic C?H Phosphorylation of N-Benzylanilines: Synthesis of α-Aminophosphonates
Jia, Xiaodong,Liu, Xiaofei,Yuan, Yu,Li, Pengfei,Hou, Wentao,He, Kaixuan
supporting information, p. 1911 - 1914 (2018/07/31)
A radical cation salt-initiated phosphorylation of N-benzylanilines was realized through an aerobic oxidation of the sp3 C?H bond, providing a series of α-aminophosphonates in high yields. An investigation of the reaction scope revealed that this mild catalyst system is superior in good functional group tolerance and high reaction efficiency. The mechanistic study implied that the cleavage of the sp3 C?H bond was involved in the rate-determining step.
PPh3-catalysed one-pot three-component syntheses of α-aminophosphonates under solvent-free conditions
Tian, You-Ping,Xu, Feng,Wang, Yi,Wang, Jian-Jun,Li, Hui-Li
experimental part, p. 78 - 80 (2009/10/02)
A simple and efficient preparation of α-aminophosphonates under relatively mild conditions by the one-pot reaction of aldehydes with amines and dialkyl phosphites using catalytic amounts of triphenylphosphine is described.
