177416-33-0Relevant academic research and scientific papers
Formation of cyclic sulfonium salts by Me3SiI-promoted intramolecular displacement of hydroxide or methoxide by sulfide. Ring contraction thiepane → thiolane
Cere, Vanda,Pollicino, Salvatore,Fava, Antonino
, p. 5989 - 5998 (1996)
A suitably positioned (1,2-, 1,4-, and 1,5-) intramolecular sulfide interferes with the iodotrimethylsilane-promoted iodine for hydroxyl substitution, as well as the related alcohol deprotection procedure (regioselective cleavage of methyl ethers). The ou
