177609-52-8Relevant academic research and scientific papers
Molecular-based electronically switchable tunnel junction devices
Collier,Jeppesen,Luo,Perkins,Wong,Heath,Stoddart
, p. 12632 - 12641 (2007/10/03)
Solid-state tunnel junction devices were fabricated from Langmuir Blodgett molecular monolayers of a bistable [2]catenane, a bistable [2]pseudorotaxane, and a single-station [2]rotaxane. All devices exhibited a (noncapacitive) hysteretic current-voltage r
Self-assembly of an amphiphilic [2]rotaxane incorporating a tetrathiafulvalene unit
Jeppesen, Jan Oskar,Perkins, Julie,Becher, Jan,Stoddart, J. Fraser
, p. 3547 - 3550 (2007/10/03)
(matrix presented) The template-directed synthesis of a [2]rotaxane, in which a π-electron deficient ring component - cyclobis(paraquat-p-phenylene) - is assembled around a π-electron rich asymmetric monopyrrolotetrathiafulvalene unit on the rod section o
Self-assembly, spectroscopic, and electrochemical properties of [n]rotaxanes
Ashton,Ballardini,Balzani,Belohradsky,Gandolfi,Philp,Prodi,Raymo,Reddington,Spencer,Stoddart,Venturi,Williams
, p. 4931 - 4951 (2007/10/03)
Synthetic approaches to self-assembling [n]rotaxanes incorporating Π- electron deficient bipyridinium-based dumbbell-shaped components and Π- electron rich hydroquinone-based macrocycles have been developed. In particular, the so-called slippage methodolo
Slippage - an Alternative Method for assembling Rotaxanes
Ashton, Peter R.,Belohradsky, Martin,Philp, Douglas,Stoddart, J. Fraser
, p. 1269 - 1274 (2007/10/02)
The exploitation of size-complementarity between the macrocyclic component and the stoppers of the cumbbell component of a rotaxane, together with stabilising noncovalent bonding interactions that create a thermodynamic trap, have permitted the development of an alternative method, which can be termed slippage, for the syntheses of rotaxanes in good yields.
