177750-77-5Relevant academic research and scientific papers
Cobalt catalyzed functionalization of unactivated alkenes: Regioselective reductive C-C bond forming reactions
Gaspar, Boris,Carreira, Erick M.
supporting information; experimental part, p. 13214 - 13215 (2010/01/21)
(Chemical Equation Presented) The cobalt catalyzed hydroaldoximation and hydrocyanooximation of unactivated alkenes is reported. Secondary and tertiary aldoximes and oximonitriles are synthesized with excellent regioselectivity under mild conditions, and conversion of the products to valuable intermediates is documented. The reactions expand the arsenal of reductive carbon-carbon bond forming reactions as well as regioselective functionalizations of unactivated double bonds.
Novel radical reaction of phenylsulfonyl oxime ethers. A free radical acylation approach
Kim, Sunggak,Lee, Ill Young,Yoon, Joo-Yong,Oh, Dong Hyun
, p. 5138 - 5139 (2007/10/03)
Although acylation represents one of the most useful and thoroughly studied reactions in organic chemistry, a successful free radical mediated acylation is not presently available. free radical carbonylation has recently been reported. This reaction allow
