177750-79-7

Upstream product

• 177750-77-5 phenyl N-(benzyloxy)methanimidothioate 
• 151451-59-1 N-benzyloxyformhydroxamic chloride 
• 72399-18-9 formaldehyde O-benzyloxime 

Downstream Products

• 1188357-18-7 2,2-dimethyl-4-phenylbutanal O-benzyl oxime 
• 667906-72-1 (E)-2-methyl-4-phenylbutanal O-benzyl oxime 
• 88459-01-2 (1s,3s)-adamantan-1-yl(phenyl)sulfide 
• 1373402-91-5 C₁₄H₃₄Si₃ 
• 1373402-88-0 C₁₇H₄₄OSi₄ 

Relevant academic research and scientific papers

Cobalt bis(acetylacetonate)–tert-butyl hydroperoxide–triethyl-silane: A general reagent combination for the Markovnikov-selective hydrofunctionalization of alkenes by hydrogen atom transfer

We show that cobalt bis(acetylacetonate) [Co(acac)2], tert-butyl hydroperoxide (TBHP), and triethylsilane (Et3SiH) constitute an inexpensive, general, and practical reagent combination to initiate a broad range of Markovnikov-selective alkene hydrofunctionalization reactions. These transformations are believed to proceed by cobalt-mediated hydrogen atom transfer (HAT) to the alkene substrate, followed by interception of the resulting alkyl radical intermediate with a SOMOphile. In addition, we report the first reductive couplings of unactivated alkenes and aryldiazonium salts by an HAT pathway. The simplicity and generality of the Co(acac)2–TBHP–Et3SiH reagent combination suggests it as a useful starting point to develop HAT reactions in complex settings.

Novel radical reaction of phenylsulfonyl oxime ethers. A free radical acylation approach

Although acylation represents one of the most useful and thoroughly studied reactions in organic chemistry, a successful free radical mediated acylation is not presently available. free radical carbonylation has recently been reported. This reaction allow