17787-26-7

Basic information

• Product Name: 3 4 5-TRIFLUOROBENZOYL CHLORIDE 97
• Synonyms: 3 4 5-TRIFLUOROBENZOYL CHLORIDE 97
• CAS NO: 17787-26-7
• Molecular Formula: C₆H₁₈Cl₂O₆P₂Pd
• Molecular Weight: 194.5383896
• Product Categories: Acid Halides;Carbonyl Compounds;Organic Building Blocks
• Mol File: 17787-26-7.mol
• Article Data: 2

Chemical Properties

• Boiling Point: 173-174 °C(lit.)
• Flash Point: 154 °F
• Appearance: /
• Density: 1.4850 g/mL at 25 °C(lit.)
• Refractive Index: n20/D 1.4900(lit.)
• CAS DataBase Reference: 3 4 5-TRIFLUOROBENZOYL CHLORIDE 97(CAS DataBase Reference)
• NIST Chemistry Reference: 3 4 5-TRIFLUOROBENZOYL CHLORIDE 97(17787-26-7)
• EPA Substance Registry System: 3 4 5-TRIFLUOROBENZOYL CHLORIDE 97(17787-26-7)

Safety Data

• Hazard Codes: C
• Statements: 34
• Safety Statements: 26-27-36/37/39-45
• RIDADR: UN 3265 8/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 17787-26-7(Hazardous Substances Data)

Upstream product

• 101-02-0 triphenyl phosphite 
• 67-56-1 methanol 
• 21264-30-2 dichloro bis(acetonitrile) palladium(II) 
• 12107-56-1 dichloro(1,5-cyclooctadiene)palladium(II) 
• 121-45-9 phosphorous acid trimethyl ester 
• 31570-04-4 tris(2,4-di-tert-butylphenyl)phosphite 
• 31502-36-0 tri(o-t-butylphenyl)phosphite 
• 30153-53-8 dichlorobis(phosphorustrichloride)palladium (II) 
• 882739-03-9 P(C₆H₃-3,5-OMe₂)3 
• 31502-35-9 tris(2-isopropylphenyl)phosphite 
• 882739-08-4 cis-[PdCl₂(P(OC₆H₃-3,5-Me₂)3)2] 

Downstream Products

• 300773-40-4 cis-[PdCl(2-(diphenylphosphinoamino)pyridine-P,N)(P(OMe)3)]Cl 

Relevant articles and documents

The influence of steric bulk on the geometry of triarylphosphite-based palladacycles and their tricyclohexylphosphine adducts

A range of complexes of the formula [PdCl2{P(OAr) 3}2] have been synthesized in order to determine the effect of steric bulk on stereochemistry, one example [PdCl 2{P(OC6H4-2-tBu)3} 2] has been structurally characterized. Three palladacyclic complexes [{Pd(μ-Cl)(κ2-P,C-P(OC6H3R)(OC 6H4R)2)}2] have been synthesized (R = H, 2-iPr, 2-tBu) and two have been characterized by crystallography (R = H and tBu). The latter adopts the expected trans geometry while the former is cis. In this case, the driving force for the cis geometry seems to be intermolecular interactions in the crystal structure which are disrupted on substitution. We also report an unusual solvolysis reaction.