177913-75-6

Basic information

• Product Name: (2R,3R,4R)-2,3,4-Tris-benzyloxy-hex-5-enal
• Synonyms: (2R,3R,4R)-2,3,4-Tris-benzyloxy-hex-5-enal
• CAS NO: 177913-75-6
• Molecular Weight: 416.517
• Mol File: 177913-75-6.mol
• Article Data: 3

Chemical Properties

• CAS DataBase Reference: (2R,3R,4R)-2,3,4-Tris-benzyloxy-hex-5-enal(CAS DataBase Reference)
• NIST Chemistry Reference: (2R,3R,4R)-2,3,4-Tris-benzyloxy-hex-5-enal(177913-75-6)
• EPA Substance Registry System: (2R,3R,4R)-2,3,4-Tris-benzyloxy-hex-5-enal(177913-75-6)

Safety Data

• Hazardous Substances Data: 177913-75-6(Hazardous Substances Data)

Upstream product

• 305834-12-2 methyl 2,3,4-tri-O-benzyl-β-D-allo-pyranoside 
• 18469-06-2 methyl β-D-allo-pyranoside 
• 100-39-0 benzyl bromide 
• 343934-72-5 (2R,3R,4R)-2,3,4-tribenzyloxy-hex-5-ene-1-al di-n-propyl dithioacetal 
• 305834-13-3 methyl 2,3,4-tri-O-benzyl-6-deoxy-6-iodo-β-D-allo-pyranoside 

Downstream Products

• 139014-28-1 3,4,5-tri-O-benzyl-1,2-dideoxy-L-ribo-hex-1-enitol 
• 195245-30-8 3,4,5-tri-O-benzyl-1,2,6-trideoxy-6-iodo-L-ribo-hex-1-enitol 
• 343934-73-6 N-(4-Bromo-phenyl)-N'-[(2S,3R,4R)-2,3,4-tris-benzyloxy-hex-5-en-(E)-ylidene]-hydrazine 

Relevant articles and documents

Cycloaddition reactions of carbohydrate derivatives. Part 8: Intramolecular cycloaddition of nitrilimines derived from sugars

Nitrilimines containing a carbon-carbon double bond were prepared in several steps from 2,3,4-tri-O-benzyl-D-xylose, D-ribose and L-arabinose derivatives and their intramolecular 1,3-dipolar cycloaddition reactions were studied. The results were examined

A new synthesis of carbapentofuranoses from carbohydrates

Carbafuranosides were synthesized in one step from various O-protected 1,2,6-trideoxy-6-iodo-hex-1-enitols by cobalt catalyzed 5-exo radical-cyclization under molecular oxygen. Yields were fair to good with interesting selectivities.