305834-13-3Relevant academic research and scientific papers
First total synthesis of 3-Epi-calystegin B2
Csuk, Rene,Reissmann, Stefan,Kluge, Ralph,Stroehl, Dieter,Korb, Claudia
, p. 317 - 323 (2011/05/07)
A straightforward chiral pool synthesis for a non-natural calystegin, 3-epi-B2, is described. Key steps of this synthesis include an ultrasound-assisted Zn-mediated tandem ring opening reaction followed by a Grubbs' catalyst-mediated ring closu
Efficient synthesis of (6-deoxy-glycopyranosid-6-yl) sulfone derivatives and their effect on Ca2+-ATPase
Mukherjee, Chinmoy,Ghosh, Swatilekha,Nandi, Pinki,Sen, Parimal C.,Misra, Anup Kumar
experimental part, p. 6012 - 6019 (2011/01/13)
Synthesis of a series of novel (6-deoxy-glycopyranosid-6-yl) sulfone derivatives has been achieved using a general synthetic strategy. Yields were excellent in every case. The synthetic compounds were evaluated for their biological potential against Casu
The cobalt-catalyzed oxygenative radical route from hexopyranosides to carbapentofuranoses
Desire, Jerome,Prandi, Jacques
, p. 3075 - 3084 (2007/10/03)
Cobalt-catalyzed radical cyclization/oxygenation of various 6-iodohex-1-enitols gave in one step the carbocyclic analogs of pentofuranoses. The reaction was run under very mild conditions and gave moderate to good yields of carbapentofuranoses within a few hours. All the possible 6-iodohex-1-enitol stereoisomers were prepared, and the influence of relative configurations and protecting groups was studied.
