17820-33-6

Upstream product

• 2999-40-8 1,3,5-triacetoxybenzene 
• 480-66-0 2,4,6-trihydroxyacetophenone 
• 108-24-7 acetic anhydride 
• 144152-27-2 1-[2,4,6-tris(acetyloxy)phenyl]ethanone 

Downstream Products

• 116345-96-1 5-hydroxy-1,3-phenylene diacetate 
• 1209470-18-7 4',6'-bis[2-(benzyloxy)benzyloxy]-2'-hydroxychalcone 
• 1209470-19-8 7-[2-(benzyloxy)benzyloxy]-5-hydroxyflavanone 
• 1209470-27-8 C₂₉H₂₄O₅ 
• 1209470-21-2 C₂₉H₂₄O₅ 
• 910619-54-4 C₂₂H₁₈O₅ 
• 1209470-16-5 C₃₆H₃₂O₆ 
• 18065-05-9 1-[2,4-bis(benzyloxy)-6-hydroxyphenyl]ethanone 
• 118971-85-0 cis acetoxy-3 -2 tetrahydropyranne 
• 118971-85-0 trans acetoxy-3 -2 tetrahydropyranne 
• 118971-83-8 trans chloro-3 -2 tetrahydropyranne 
• 118971-83-8 cis chloro-3 -2 tetrahydropyranne 
• 119692-03-4 2',4'-diacetoxy-6'-methoxyacetophenone 

Relevant academic research and scientific papers

Total synthesis of 3′,3?-binaringenin and related biflavonoids

The synthesis of natural 3++,3?-binaringenin and four related biflavonoids was performed in good overall yield (15-35%) starting from readily available phloroglucinol and 4-hydroxy- or 4-methoxybenzaldehyde. Preliminary results indicate that some of these compounds have an interesting activity against S. aureus. Georg Thieme Verlag Stuttgart.

Acidic rearrangement of (benzyloxy)chalcones: A short synthesis of chamanetin

Treatment of (benzyloxy)chalcones with trifluoroacetic acid in refluxing chloroform gave several new benzyl(hydroxy)flavanones in high yields and good regioselectivities. By using this procedure, we prepared the natural compound chamanetin in good yield from readily available reagents. Georg Thieme Verlag Stuttgart - New York.

BF3·OEt2 mediated regioselective deacetylation of polyacetoxyacetophenones and its application in the synthesis of natural products

We have developed an efficient method to regioselectively deacetylate polyacetoxyacetophenones using BF3·OEt2 in excellent yields and demonstrated the application of the procedure in the synthesis of natural products.

Deacetylation of activated acetophenones with tin(IV) chloride

Activated acetophenones were deacetylated by treatment with an excess of tin(IV) chloride in 1,2-dichloroethane.

Syntheses d'aryltetrahydropyrannyl ethers

L'addition de methoxyphenols 1 sur le dihydropyranne en milieu acide donne des produits C- et/ou O-tetrahydropyrannyles 3 et 4 dont le pourcentage est fonction du nombre de substituants methoxy et de la force du catalyseur acide.Les aryl tetrahydropyranny

PHOTO-FRIES REARRANGEMENT: REARRANGEMENT OF ACETOXYBENZENE DERIVATIVES

Photo-Fries rearrangement of 1,4-diacetoxybenzene, 1,3,5-triacetoxybenzene, 1,2,3-triacetoxybenzene and 1,2,4-triacetoxybenzene gave the corresponding mono- and di-C-acetyl migrated products.