178458-31-6Relevant academic research and scientific papers
Excellent chiral introduction by diene iron-tricarbonyl moiety. III: Asymmetric synthesis of hydroxyethylidene dipeptide isostere using a diastereoselective 1,2-nucleophilic addition of organocerium reagents into a 1-azatriene Fe(CO)3 complex
Takemoto, Yoshiji,Takeuchi, Jun,Matsui, Eiki,Iwata, Chuzo
, p. 948 - 955 (1996)
A 1-iminobutadiene-iron tricarbonyl [Fe(CO)3] complex (1) reacts with various organometallic nucleophiles in a stereoselective manner, and especially, by use of organocerium reagents, only single secondary amine complexes (2) were obtained in g
