Excellent chiral introduction by diene iron-tricarbonyl moiety. III: Asymmetric synthesis of hydroxyethylidene dipeptide isostere using a diastereoselective 1,2-nucleophilic addition of organocerium reagents into a 1-azatriene Fe(CO)3 complex

DOI: 10.1248/cpb.44.948

Source and publish data:

Chemical and Pharmaceutical Bulletin p. 948 - 955 (1996)

Update date:2022-08-02

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Authors:

Takemoto, Yoshiji

Takeuchi, Jun

Matsui, Eiki

Iwata, Chuzo

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Article abstract of DOI:10.1248/cpb.44.948

A 1-iminobutadiene-iron tricarbonyl [Fe(CO)₃] complex (1) reacts with various organometallic nucleophiles in a stereoselective manner, and especially, by use of organocerium reagents, only single secondary amine complexes (2) were obtained in g

Full text of DOI:10.1248/cpb.44.948

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