17872-59-2Relevant academic research and scientific papers
A General Approach to Quaternary Center Construction from Couplings of Unactivated Alkenes and Acyl Xanthates
Jenkins, Ernest N.,Czaplyski, William L.,Alexanian, Erik J.
supporting information, p. 2350 - 2353 (2017/05/12)
A general, radical-mediated approach to quaternary center construction using unactivated alkenes as coupling partners is reported. In this strategy, acyl xanthates, readily accessed from carboxylic acids, serve as precursors to tertiary radicals. This strategy leverages the unique reactivity of xanthates to participate in efficient radical-mediated additions to unactivated alkenes, expanding the scope of quaternary center construction.
Synthesis, characterization, and 1H NMR self-diffusion studies of dendritic aliphatic polyesters based on 2,2-bis(hydroxymethyl)propionic acid and 1,1,1-tris(hydroxyphenyl)ethane
Ihre, Henrik,Hult, Anders,S?derlind, Erik
, p. 6388 - 6395 (2007/10/03)
Dendritic aliphatic polyesters of one, two, three, and four generations (M(w): 906, 1856, 3754, and 7549 g/mol) were synthesized in the convergent fashion, using 2,2-bis(hydroxymethyl)propionic acid as building block and 1,1,1-tris(hydroxyphenyl)ethane as
