17877-22-4

Basic information

• Product Name: Trimethyl[(2-methylpentyl)oxy]silane
• Synonyms: Trimethyl[(2-methylpentyl)oxy]silane
• CAS NO: 17877-22-4
• Molecular Weight: 0
• Mol File: 17877-22-4.mol
• Article Data: 1

Chemical Properties

• Appearance: /
• CAS DataBase Reference: Trimethyl[(2-methylpentyl)oxy]silane(CAS DataBase Reference)
• NIST Chemistry Reference: Trimethyl[(2-methylpentyl)oxy]silane(17877-22-4)
• EPA Substance Registry System: Trimethyl[(2-methylpentyl)oxy]silane(17877-22-4)

Safety Data

• Hazardous Substances Data: 17877-22-4(Hazardous Substances Data)

Upstream product

• 75-77-4 chloro-trimethyl-silane 
• 187737-37-7 propene 
• 75-24-1 trimethylaluminum 
• 105-30-6 2-methylpentan-1-ol 

Relevant articles and documents

Diastereoselective synthesis of functionally substituted alkene dimers and oligomers, catalysed by chiral zirconocenes

The research addresses the reaction of terminal alkenes and propene with AlR3 (R = Me, Et) in the presence of chiral Zr complexes, rac-[Y(η5-C9H10)2]ZrCl2 (Y = C2H4, SiMe2) or (NMI)2ZrCl2 (NMI- η5–neomenthylindenyl), and methylaluminoxane. The effect of reaction conditions, catalyst and trialkylalane structure on the substrate conversion and the reaction chemo- and stereoselectivity has been studied. The reaction predominantly goes via the stage of alkene methyl(ethyl)zirconation with subsequent introduction of substrate molecules into the Zr-C bond. As a result, a diastereoselective one-pot method for the synthesis of functionally substituted linear terminal alkene dimers and propene oligomers was developed.