17902-99-7Relevant academic research and scientific papers
Synthesis and crystal structure of oxo-bridged binuclear titanium complex [{Ti(acac)2Cl}{TiCp2(Cl)}(μ-O)] and its catalytic reactions toward silation of aldehyde
Yun, Sock-Sung,Suh, Il-Hwan,Kim, Eun Hee,Choi, Byong-Jin,Lee, Samkeun
, p. 16 - 18 (2001)
Reaction of [Cp2TiCl2] with two equivalents of 2,4-pentanedione in the presence of one equivalent of NEt3 in CH3CN at room temperature yielded oxo-bridged binuclear titanium complex [{Ti(acac)2Cl}{TiC
Photoactivated silicon-oxygen and silicon-nitrogen heterodehydrocoupling with a commercially available iron compound
Cibuzar, Michael P.,Hammerton, James,Reuter, Matthew B.,Waterman, Rory
supporting information, p. 2972 - 2978 (2020/03/13)
Silicon-oxygen and silicon-nitrogen heterodehydrocoupling catalyzed by the commercially available cyclopentadienyl dicarbonyl iron dimer [CpFe(CO)2]2 (1) under photochemical conditions is reported. Reactions between alcohols and PhSi
Pollution-free method for preparing diphenyldiethoxysilane
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Paragraph 0064-0065; 0067, (2019/01/08)
The invention relates to a synthetic method of phenyl alkoxysilane, which includes: dissolving phenyl chlorosilane in an organic solvent, and adding an alcohol-alkoxide solution, performing a reactionin an inert atmosphere; when the reaction is carried out to a certain degree, adding a sodium alkoxide solution, continuously carrying out the reaction; when the reaction is finished, distilling thereaction product to form the phenyl alkoxysilane.
Environment-friendly preparation method of diphenyldimethoxysilane
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Paragraph 0064; 0065; 0066; 0067, (2019/01/08)
The invention relates to a preparation method of phenyl alkoxysilane, which includes: dissolving phenyl chlorosilane in an organic solvent, adding alcohol-alkoxide solution and performing a reaction in an inert atmosphere; when the reaction is carried out to a certain degree, adding a sodium alkoxide solution, continuously carrying out the reaction; when the reaction is finished, distilling the reaction product to form the phenyl alkoxysilane.
Catalytic Dehydrogenative Coupling of Hydrosilanes with Alcohols for the Production of Hydrogen On-demand: Application of a Silane/Alcohol Pair as a Liquid Organic Hydrogen Carrier
Ventura-Espinosa, David,Carretero-Cerdán, Alba,Baya, Miguel,García, Hermenegildo,Mata, Jose A.
supporting information, p. 10815 - 10821 (2017/08/18)
The compound [Ru(p-cym)(Cl)2(NHC)] is an effective catalyst for the room-temperature coupling of silanes and alcohols with the concomitant formation of molecular hydrogen. High catalyst activity is observed for a variety of substrates affording quantitative yields in minutes at room temperature and with a catalyst loading as low as 0.1 mol %. The coupling reaction is thermodynamically and, in the presence of a Ru complex, kinetically favourable and allows rapid molecular hydrogen generation on-demand at room temperature, under air, and without any additive. The pair silane/alcohol is a potential liquid organic hydrogen carrier (LOHC) for energy storage over long periods in a safe and secure way. Silanes and alcohols are non-toxic compounds and do not require special handling precautions such as high pressure or an inert atmosphere. These properties enhance the practical applications of the pair silane/alcohol as a good LOHC in the automotive industry. The variety and availability of silanes and alcohols permits a pair combination that fulfils the requirements for developing an efficient LOHC.
Hydrolytic Etherification of Phenyltrichlorosilane and Structure of Reaction Products
Kuz'menko, N. Ya.
, p. 516 - 522 (2007/10/03)
Hydrolytic etherification of phenyltrichlorosilane by C1-C4 primary alcohols was studied. The effect of the concentration and nature of alcohol on the structure and properties of oligomeric polyphenyl-alkoxysilanes were examined.
