179072-67-4

Upstream product

• 179072-66-3 phenyl 2,4,6-tri-O-benzyl-3-O-chloroacetyl-1-thio-β-D-galactopyranoside 
• 16758-34-2 1-thiophenyl-β-D-galactopyranoside 
• 100-39-0 benzyl bromide 
• 179072-63-0 phenyl 3-O-(4-methoxybenzyl)-1-thio-β-D-galactopyranoside 
• 179072-65-2 phenyl 2,4,6-tri-O-benzyl-1-thio-β-D-galactopyranoside 
• 819798-47-5 phenyl 2,4,6-tri-O-benzyl-3-O-p-methoxybenzyl-1-thio-β-D-glucopyranoside 

Downstream Products

• 179072-55-0 2,4,6-tri-O-benzyl-α,β-D-galactopyranosyl fluoride 
• 179072-60-7 C₆₈H₇₉NO₂₀ 
• 179072-56-1 Acetic acid (2R,3R,4R,5R,6S)-3-acetoxy-2-acetoxymethyl-6-((2R,3S,4S,5R)-3,5-bis-benzyloxy-2-benzyloxymethyl-6-fluoro-tetrahydro-pyran-4-yloxy)-5-(1,3-dioxo-1,3-dihydro-isoindol-2-yl)-tetrahydro-pyran-4-yl ester 
• 179072-59-4 C₇₃H₈₅NO₂₂ 
• 179072-58-3 C₇₁H₇₃NO₂₁S 

Relevant academic research and scientific papers

Orthogonal glycosylation reactions on solid phase and synthesis of a library consisting of a complete set of fucosyl galactose isomers

A dream team: Orthogonal glycosylation and solid-phase synthesis were shown to be an excellent combination for polysaccharide synthesis (see scheme). The method was applied to generate a complete library of structural isomers with an L-fucosyl-D-galactose

Orthogonal glycosylation strategy in synthesis of extended blood group B determinant

The orthogonal glycosylation strategy was applied for the synthesis of extended blood type B determinant (2) of a novel glycolipid 1. Key features in the synthesis are 1) four monosaccharide units were synthesized as either glycosyl fluoride or thioglycoside to be engaged to the orthogonal glycosylation strategy and 2) all necessary manipulations were completed at the monosaccharide level, therefore, manipulations during the elongation of sugar chain were minimized.