17921-71-0

Basic information

• Product Name: (α,α-dibromotolyl)-α-trimethylsilane
• Synonyms: (α,α-dibromotolyl)-α-trimethylsilane
• CAS NO: 17921-71-0
• Molecular Weight: 322.115
• Mol File: 17921-71-0.mol
• Article Data: 4

Chemical Properties

• CAS DataBase Reference: (α,α-dibromotolyl)-α-trimethylsilane(CAS DataBase Reference)
• NIST Chemistry Reference: (α,α-dibromotolyl)-α-trimethylsilane(17921-71-0)
• EPA Substance Registry System: (α,α-dibromotolyl)-α-trimethylsilane(17921-71-0)

Safety Data

• Hazardous Substances Data: 17921-71-0(Hazardous Substances Data)

Upstream product

• 770-09-2 benzyltrimethylsilane 
• 128-08-5 N-Bromosuccinimide 

Downstream Products

• 62713-14-8 ethyl (Z)-3-phenyl-3-(trimethylsilyl)prop-2-enoate 
• 80515-48-6 C-Phenyl-C-trimethylsilanyl-methylene-oxonium 
• 16804-70-9 cumyl cation 
• 53173-00-5 α-hydroxy-α-trimethylsilylethylbenzene 
• 397251-74-0 [(S)-((R)-1-Allyl-hexyloxy)-phenyl-methyl]-trimethyl-silane 
• 397251-79-5 ((S)-1-Cyclohexyl-but-3-enyloxymethyl)-benzene 
• 397251-80-8 C₁₉H₂₂O 
• 397251-81-9 (R)-4-(benzyloxy)non-1-ene 
• 397251-71-7 (S)-α-(trimethylsilyloxy)benzyltrimethylsilane 
• 31280-60-1 (S)-(-)-α-(Trimethylsilyl)benzenemethanol 
• 397251-72-8 [(S)-((S)-1-Cyclohexyl-but-3-enyloxy)-phenyl-methyl]-trimethyl-silane 
• 397251-73-9 Trimethyl-[(S)-((R)-1-phenethyl-but-3-enyloxy)-phenyl-methyl]-silane 
• 397251-78-4 Trimethyl-{(S)-phenyl-[(S)-1-((E)-styryl)-but-3-enyloxy]-methyl}-silane 

Relevant articles and documents

Controllable one-pot synthesis for scaffold diversity: Via visible-light photoredox-catalyzed Giese reaction and further transformation

This study presents a controllable one-pot synthesis for constructing valuable scaffolds (alcohols, 2,3-dihydrofurans, α-cyano-γ-butyrolactones, and γ-butyrolactones) via a visible-light photoredox-catalyzed Giese reaction and further transformation. This

Optically pure α-(trimethylsilyl)benzyl alcohol: A practical chiral auxiliary for oxocarbenium ion reactions

(matrix presented) Enantiopure (S)-α-(trimethylsilyl)benzyl alcohol (98% ee) was prepared by Noyori's transfer hydrogenation of benzoyltrimethylsilane. The corresponding trimethylsilyl ether was subjected to Marko's silyl modified Sakurai conditions with