397251-74-0

Upstream product

• 66-25-1 hexanal 
• 397251-71-7 (S)-α-(trimethylsilyloxy)benzyltrimethylsilane 
• 762-72-1 allyl-trimethyl-silane 
• 31280-60-1 (S)-(-)-α-(Trimethylsilyl)benzenemethanol 
• 142-61-0 Hexanoyl chloride 
• 5908-41-8 benzoyltrimethylsilane 
• 770-09-2 benzyltrimethylsilane 
• 17921-71-0 (α,α-dibromotolyl)-α-trimethylsilane 

Downstream Products

• 397251-81-9 (R)-4-(benzyloxy)non-1-ene 

Relevant academic research and scientific papers

Diastereoselective additions of nucleophiles to α-acetoxy ethers using the α-(trimethylsilyl)benzyl auxiliary

(Matrix presented) We report the diastereoselective addition of a variety of nucleophiles to α-(trimethylsilyl)benzyl-substituted oxocarbenium ions. The oxocarbenium ions are generated from α-acetoxy ethers, which are easily prepared via reductive acetyla

Optically pure α-(trimethylsilyl)benzyl alcohol: A practical chiral auxiliary for oxocarbenium ion reactions

(matrix presented) Enantiopure (S)-α-(trimethylsilyl)benzyl alcohol (98% ee) was prepared by Noyori's transfer hydrogenation of benzoyltrimethylsilane. The corresponding trimethylsilyl ether was subjected to Marko's silyl modified Sakurai conditions with