397251-81-9Relevant academic research and scientific papers
Absolute configuration assignment by asymmetric syntheses of the homalium alkaloids (?)-(R, R, R)-hoprominol and (?)-(4′ S,4″ R,2? R)-Hopromalinol
Davies, Stephen G.,Lee, James A.,Roberts, Paul M.,Stonehouse, Jeffrey P.,Thomson, James E.
, p. 9724 - 9737 (2013/01/15)
The conjugate addition of lithium (R)-N-(3-chloropropyl)-N-(α- methylbenzyl)amide to α,β-unsaturated esters was used as the key step in the syntheses of all possible diastereoisomers of the homalium alkaloids hoprominol and hopromalinol. Comparison of the
Optically pure α-(trimethylsilyl)benzyl alcohol: A practical chiral auxiliary for oxocarbenium ion reactions
Cossrow, Jennifer,Rychnovsky, Scott D.
, p. 147 - 150 (2007/10/03)
(matrix presented) Enantiopure (S)-α-(trimethylsilyl)benzyl alcohol (98% ee) was prepared by Noyori's transfer hydrogenation of benzoyltrimethylsilane. The corresponding trimethylsilyl ether was subjected to Marko's silyl modified Sakurai conditions with
