1795-09-1Relevant articles and documents
HYDROGENATION OF SUBSTITUTED THIOPHENES BY THE Zn-H2SO4 SYSTEM
Latypova, F. M.,Lyakhovetskii, Yu. I.,Lyapina, N. K.,Parnes, Z. N.
, p. 1331 (1985)
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Rigau et al.
, p. 3655,3656, 3657 (1970)
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E-H (E = R3Si or H) bond activation by B(C6F 5)3 and heteroarenes; Competitive dehydrosilylation, hydrosilylation and hydrogenation
Curless, Liam D.,Clark, Ewan R.,Dunsford, Jay J.,Ingleson, Michael J.
supporting information, p. 5270 - 5272 (2014/05/06)
In the presence of B(C6F5)3 five-membered heteroarenes undergo dehydrosilylation and hydrosilylation with silanes. The former, favoured on addition of a weak base, produces H2 as a by-product making the process catalytic in B(C6F5) 3 but also enabling competitive heteroarene hydrogenation. the Partner Organisations 2014.
Hydrogen storage using heterocyclic compounds: The hydrogenation of 2-methylthiophene
Zhao,Oyama,Naeemi
scheme or table, p. 172 - 184 (2010/11/05)
Alkyl substituted thiophenes are promising candidates for hydrogen carriers, as their dehydrogenation reactions are known to occur under mild conditions. Four types of catalysts, including supported noble metals, bimetallic noble metals, transition metal