17972-13-3

Basic information

• Product Name: N-methyl-1-(p-tolyl)methanimine
• Synonyms: Methanamine, N-[(4-methylphenyl)methylene]-
• CAS NO: 17972-13-3
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.1903
• Mol File: 17972-13-3.mol
• Article Data: 27

Chemical Properties

• Boiling Point: 204.11°C at 760 mmHg
• Flash Point: 68.662°C
• Density: 0.878g/cm³
• Vapor Pressure: 0.383mmHg at 25°C
• Refractive Index: 1.494
• CAS DataBase Reference: N-methyl-1-(p-tolyl)methanimine(CAS DataBase Reference)
• NIST Chemistry Reference: N-methyl-1-(p-tolyl)methanimine(17972-13-3)
• EPA Substance Registry System: N-methyl-1-(p-tolyl)methanimine(17972-13-3)

Safety Data

• Hazardous Substances Data: 17972-13-3(Hazardous Substances Data)

Upstream product

• 111291-48-6 C₁₆H₁₆F₃NO₃S 
• 593-51-1 methylamine hydrochloride 
• 104-87-0 4-methyl-benzaldehyde 
• 75-52-5 nitromethane 
• 53699-34-6 (E)-N-methyl[(4-methylphenyl)methylidene]amine 
• 96-31-1 N,N'-Dimethylurea 
• 699-04-7 N-methyl-p-methylbenzylamine 
• 78817-35-3 C₁₈H₂₃N₃ 
• 36342-33-3 C₉H₁₂N₂O₂ 
• 74-89-5 methylamine 

Downstream Products

• 66380-03-8 N-methyl-C-(4-methylphenyl)-glycine hydrochloride 
• 1588533-93-0 3,6,6-trimethyl-2-(4-methylphenyl)-1,3-oxazinan-4-one 
• 1178122-16-1 C₁₇H₂₁NO 
• 1415240-23-1 C₁₇H₁₉NO 
• 543737-30-0 C₁₇H₁₉N 
• 1305337-30-7 C₆H₃FOCHNC₆H₃(CH(CH₃)2)2Ni(CO)COCH₃ 

Relevant articles and documents

Enantioselective Reductive Coupling of Imines Templated by Chiral Diboron

We herein report a general, practical, and highly efficient method for asymmetric synthesis of a wide range of chiral vicinal diamines via reductive coupling of imines templated by chiral diboron. The protocol features high enantioselectivity and stereospecificity, mild reaction conditions, simple operating procedures, use of readily available starting materials, and a broad substrate scope. The method signifies the generality of diboron-enabled [3,3]-sigmatropic rearrangement.

Method for synthesizing imine by catalytic oxidation of asymmetric secondary amine in presence of visible light

The invention belongs to the technical field of chemical engineering and pharmaceutical industry, and particularly relates to a method for synthesizing imine by catalytic oxidation of asymmetric secondary amine in the presence of visible light. With aza-metalloporphyrin containing sulfur as a visible light catalyst, 1,8-diazabicycloundecene-7-alkene as an auxiliary agent, and oxygen as an oxidant,asymmetric secondary amine is subjected to catalytic oxidation under irradiation of visible light of lambda being larger than or equal to 420nm, so as to obtain the oxidation product imine. A new andefficient imine production way is provided.

Synthesis of N-methyl imines in the presence of poly(N-vinylpyridine) as a reusable solid base catalyst by a mechanochemical process

The synthesis of N-methyl imines was performed in the presence of catalytic amounts of poly(4-vinylpyridine) in high yields and rapidly at room temperature by a ball milling process. This new method has some advantages including good yields for relatively unreactive carbonyl compounds and short reaction times as well as being green in terms of avoiding the use of toxic reagents and solvents. The major advantage of this process is that the catalyst can be easily regenerated and reused several times without any significant loss of activity.