N,4-Dimethylbenzenemethanimine

Base Information

• Chemical Name: N,4-Dimethylbenzenemethanimine
• CAS No.: 17972-13-3
• Molecular Formula: C₉H₁₁N
• Molecular Weight: 133.193
• DSSTox Substance ID: DTXSID201276406
• Nikkaji Number: J976.895E
• Mol file: 17972-13-3.mol

Synonyms:17972-13-3;N,4-Dimethylbenzenemethanimine;SCHEMBL862550;SCHEMBL10356855;SCHEMBL21527117;DTXSID201276406;N-[(4-Methylphenyl)methylene]methanamine

Chemical Property of N,4-Dimethylbenzenemethanimine

Chemical Property:

• Vapor Pressure: 0.383mmHg at 25°C
• Boiling Point: 204.11oC at 760 mmHg
• Flash Point: 68.662oC
• PSA: 12.36000
• Density: 0.878g/cm3
• LogP: 2.04370
• XLogP3: 2.3
• Hydrogen Bond Donor Count: 0
• Hydrogen Bond Acceptor Count: 1
• Rotatable Bond Count: 1
• Exact Mass: 133.089149355
• Heavy Atom Count: 10
• Complexity: 110

Purity/Quality:

Safty Information:

• Pictogram(s):  
• Hazard Codes: 

MSDS Files:

SDS file from LookChem

Useful:

• Canonical SMILES: CC1=CC=C(C=C1)C=NC

Technology Process of N,4-Dimethylbenzenemethanimine

There total 10 articles about N,4-Dimethylbenzenemethanimine which guide to synthetic route it. The literature collected by LookChem mainly comes from the sharing of users and the free literature resources found by Internet computing technology. We keep the original model of the professional version of literature to make it easier and faster for users to retrieve and use. At the same time, we analyze and calculate the most feasible synthesis route with the highest yield for your reference as below:

synthetic route:

Reference yield: 100.0%

4-methyl-benzaldehyde (104-87-0) + methylamine (74-89-5) → p-methylbenzylidene-methylamine (17972-13-3,29086-13-3,53699-34-6)

Guidance literature:

at 20 ℃; for 12h;

DOI:10.1055/s-0029-1218796

Reference yield: 94.0%

methylamine hydrochloride (593-51-1) + 4-methyl-benzaldehyde (104-87-0) → p-methylbenzylidene-methylamine (17972-13-3,29086-13-3,53699-34-6)

Guidance literature:

With 1,1'-(1,4-butanediyl)bis(imidazole); In neat (no solvent); at 20 ℃; for 10h; Milling;

DOI:10.1071/CH18408

Reference yield: 55.0%

N,N'-Dimethylurea (96-31-1) + 4-methyl-benzaldehyde (104-87-0) → p-methylbenzylidene-methylamine (17972-13-3,29086-13-3,53699-34-6)

Guidance literature:

With Montmorillonite K₁₀; at 20 - 120 ℃; for 0.166667h; microwave irradiation;

DOI:10.1055/s-2006-926429

upstream raw materials:

4-methyl-benzaldehyde

methylamine

C₉H₁₂N₂O₂

C₁₆H₁₆F₃NO₃S

Downstream raw materials:

cis-N-methyl-3-(p-methylphenyl)-4-carboxy-3,4-dihydro-1(2H)-isoquinolone

trans-N-methyl-3-(p-methylphenyl)-4-carboxy-3,4-dihydro-1(2H)-isoquinolone

trans-N-methyl-4-carboxy-5-(p-methylphenyl)-4-phenyl-2-pyrrolidinone

cis-N-methyl-4-carboxy-5-(p-methylphenyl)-4-phenyl-2-pyrrolidinone