17983-41-4Relevant academic research and scientific papers
Acrylonitrile compound as well as preparation method and application thereof
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Paragraph 0185-0187, (2021/09/08)
The invention relates to the field of insecticides and acaricides, and discloses an acrylonitrile compound as well as a preparation method and application thereof, and the trimethylsilyl phenyl acrylonitrile compound has a structure as shown in a formula (I). The acrylonitrile compound with a novel structure provided by the invention can be applied to prevention and control of agricultural pest mites.
Design, synthesis and acaricidal activities of Cyflumetofen analogues based on carbon-silicon isosteric replacement
Beadle, Ryan,Cheng, Jiagao,Earley, Fergus G.,Li, Zhong,Maienfisch, Peter,Zhou, Cong
, (2020/04/30)
The application of a carbon-silicon bioisosteric replacement strategy to find new acaricides with improved properties led to the discovery of Sila-Cyflumetofen 6B, a novel and highly potent acaricide. The essential t-butyl group in the beta-ketonitrile ac
Silicon acyl acetonitrile compound as well as preparation method and application thereof (by machine translation)
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Paragraph 0192; 0196-0198, (2019/12/25)
In particular, the present invention relates to a compound containing a, silicon acyl acetonitrile compound, or a stereoisomer thereof, or a. stereoisomer thereof, or a salt thereof, wherein the compound of the, present invention I I has excellent, acaric
Synthesis of α-Aryl nitriles through palladium-catalyzed decarboxylative coupling of cyanoacetate salts with aryl halides and triflates
Shang, Rui,Ji, Dong-Sheng,Chu, Ling,Fu, Yao,Liu, Lei
supporting information; experimental part, p. 4470 - 4474 (2011/06/24)
Worth its salt: The palladium-catalyzed decarboxylative coupling of the cyanoacetate salt as well as its mono- and disubstituted derivatives with aryl chlorides, bromides, and triflates is described (see scheme). This reaction is potentially useful for the preparation of a diverse array of α-aryl nitriles and has good functional group tolerance. S-Phos=2-(2,6- dimethoxybiphenyl)dicyclohexylphosphine), Xant-Phos=4,5-bis(diphenylphosphino)- 9,9-dimethylxanthene. Copyright
