18001-80-4Relevant academic research and scientific papers
(Aminomethyl)pyridine Complexes for the Cobalt-Catalyzed Anti-Markovnikov Hydrosilylation of Alkoxy- or Siloxy(vinyl)silanes with Alkoxy- or Siloxyhydrosilanes
Lee, Kangsang L.
supporting information, p. 3665 - 3669 (2017/03/21)
Cobalt-catalyzed anti-Markovnikov reactions that involve siloxy- or alkoxy(vinyl)silanes and siloxy- or alkoxyhydrosilanes are disclosed. More than 25 new cobalt–(aminomethyl)pyridine complexes were developed as catalysts for the hydrosilylation of indust
Alkoxylation of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes
Lakhtin,Nosova,Kisin,Ivanov,Chernyshev
, p. 1252 - 1254 (2007/10/03)
Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes MenCl3-nSi-Z-SiCl3-nMen (Z = CH=CH, C=C; n = 0-2) with ethanol and acetoxime were studied. Novel alkoxy-and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge.
